期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 64, 页码 9026-9029出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02772k
关键词
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资金
- Japan Society of the Promotion of Science (JSPS) [JP18H05262, JP22H05005, JP22K05128]
- Kyoto University Research Development Program
- Innovation Inspired by Nature'' Research Support Program, SEKISUI CHEMICAL CO., LTD
In this study, a flexible porous coordination polymer (PCP) containing nitroxyl radicals was prepared to achieve controllable size-selective aerobic oxidation of alcohols by reversible switching between large- and contracted-pore configurations in response to solvent change.
The ability of flexible porous coordination polymers (PCPs) to change their structure in response to various stimuli has not been exploited in the design of tunable-selectivity catalysts. Herein, we make use of this ability and prepare nitroxyl radical-containing flexible PCP that can reversibly switch between large- and contracted-pore configurations in response to solvent change and thus promote the controllable size-selective aerobic oxidation of alcohols.
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