Progress in the self-assembly of organic/inorganic polyhedral oligomeric silsesquioxane (POSS) hybrids

This Review describes recent progress in the self-assembly of organic/inorganic POSS hybrids derived from mono-, di-, and multi-functionalized POSS cages. We highlight the self-assembled structures and physical properties of giant surfactants and chain-end- and side-chain-type hybrids derived from mono-functionalized POSS cages; main-chain-type hybrids derived from di-functionalized POSS cages; and star-shaped hybrids derived from multi-functionalized POSS cages; with various polymeric attachments, including polystyrene, poly(methyl methacrylate), phenolic, PVPh, and polypeptides.

Automated summary

This review presents recent progress in the self-assembly of organic/inorganic POSS hybrids, highlighting various self-assembled structures and physical properties of hybrids derived from different types and functionalities of POSS cages. These studies are of great importance for understanding and applying the potential applications of POSS hybrids in materials science.