期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 20, 期 34, 页码 6707-6720出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob01080a
关键词
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资金
- Swedish Research Council [2021-05551]
- Formas [2021-00678]
- Swedish Foundation for Strategic Research [FFL21-0005]
- Stiftelsen Olle Engkvist Byggmastare
- Magnus Bergvalls stiftelse
- Stiftelsen Lars Hiertas Minne
- KTH Royal Institute of Technology
- Forte [2021-00678] Funding Source: Forte
- Formas [2021-00678] Funding Source: Formas
- Swedish Research Council [2021-05551] Funding Source: Swedish Research Council
This article provides a comprehensive overview of electrochemically driven protocols for C-F bond activation and functionalization in synthesis, including the use of photoelectrochemical strategies.
Fluorinated organic compounds are common among pharmaceuticals, agrochemicals and materials. The significant strength of the C-F bond results in chemical inertness that, depending on the context, is beneficial, problematic or simply a formidable synthetic challenge. Electrosynthesis is a rapidly expanding methodology that can enable new reactivity and selectivity for cleavage and formation of chemical bonds. Here, a comprehensive overview of synthetically relevant electrochemically driven protocols for C-F bond activation and functionalization is presented, including photoelectrochemical strategies.
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