期刊
JOURNAL OF APPLIED CRYSTALLOGRAPHY
卷 49, 期 -, 页码 2021-2030出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600576716014904
关键词
small-angle X-ray scattering; SANS; ultra-small-angle X-ray scattering; USANS; rock; CO2 sequestration; porosity
资金
- Laboratory Directed Research and Development Program
- Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy (DOE)
- National Science Foundation [DMR-0944772]
- Indiana Geological Survey from Battelle Memorial Institute under a DOE contract for the Midwest Regional Carbon Sequestration Partnership (MRCSP)
- Central Analytical Research Facility
- Science and Engineering Faculty of the Queensland University of Technology
Small-angle neutron scattering (SANS) and ultra-small-angle neutron scattering (USANS) have been used to study a carbonate rock from a deep saline aquifer that is a potential candidate as a storage reservoir for CO2 sequestration. A new methodology is developed for estimating the fraction of accessible and inaccessible pore volume using SANS/USANS measurements. This method does not require the achievement of zero average contrast for the calculation of accessible and inaccessible pore volume fraction. The scattering intensity at high Q increases with increasing CO2 pressure, in contrast with the low-Q behaviour where the intensity decreases with increasing pressure. Data treatment for high-Q scattering at different pressures of CO2 is also introduced to explain this anomalous behaviour. The analysis shows that a significant proportion of the pore system consists of micropores (< 20 angstrom) and that the majority (80%) of these micropores remain inaccessible to CO2 at reservoir pressures.
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