期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 66, 页码 9254-9257出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02673b
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In this study, the reactions of 1,5-diazabicyclo[3.2.2]nonane (3.2.2-dabcn) with rubidium halides were investigated, resulting in the formation of two 3D molecular ferroelectrics.
Compared with the spherical molecule 1,4-diazoniabicyclo[2.2.2]-octane (2.2.2-dabco), 1,5-diazabicyclo[3.2.2]nonane (3.2.2-dabcn) bears a lower symmetry and larger size. As expected, reactions of 3.2.2-dabcn with rubidium halides gave two 3D molecular ferroelectrics [3.2.2-H(2)dabcn]RbX3 (X = Br for 1; X = I for 2) with T-c at 342 K (1) and 293 K (2).
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