4.8 Article

Molecular nanoribbon gels

期刊

CHEMICAL SCIENCE
卷 13, 期 36, 页码 10773-10778

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc02637f

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资金

  1. Basque Science Foundation for Science (Ikerbasque)
  2. POLYMAT
  3. University of the Basque Country
  4. Diputacion de Guipuzcoa
  5. Gobierno Vasco [PIBA_2022_1_0031]
  6. Gobierno Vasco (BERC programme)
  7. Gobierno de Espana (MCIN/AEI) [PID2021-124484OB-I00, CEX2020-001067-M]
  8. Agencia Estatal de Investigacion [PCI2022-132921]
  9. European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme [722951]
  10. European Union's Horizon 2020 research and innovation programme [899895]
  11. European Union under the Horizon Europe grant [101046231]
  12. Horizon Europe - Pillar III [101046231] Funding Source: Horizon Europe - Pillar III

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This study demonstrates that twisted molecular nanoribbons can self-assemble into ordered gels, and their morphologies and sol-gel transitions vary with the length of the nanoribbons. The nanoribbon gels also exhibit red fluorescence and pseudoconductivity values in the same range as current state-of-the-art gels.
Herein, we show that twisted molecular nanoribbons with as many as 322 atoms in the aromatic core are efficient gelators capable of self-assembling into ordered pi-gels with morphologies and sol-gel transitions that vary with the length of the nanoribbon. In addition, the nanoribbon gels show a red fluorescence and also pseudoconductivity values in the same range as current state-of-the-art pi-gels.

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