期刊
CHEMICAL SCIENCE
卷 13, 期 36, 页码 10773-10778出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc02637f
关键词
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资金
- Basque Science Foundation for Science (Ikerbasque)
- POLYMAT
- University of the Basque Country
- Diputacion de Guipuzcoa
- Gobierno Vasco [PIBA_2022_1_0031]
- Gobierno Vasco (BERC programme)
- Gobierno de Espana (MCIN/AEI) [PID2021-124484OB-I00, CEX2020-001067-M]
- Agencia Estatal de Investigacion [PCI2022-132921]
- European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme [722951]
- European Union's Horizon 2020 research and innovation programme [899895]
- European Union under the Horizon Europe grant [101046231]
- Horizon Europe - Pillar III [101046231] Funding Source: Horizon Europe - Pillar III
This study demonstrates that twisted molecular nanoribbons can self-assemble into ordered gels, and their morphologies and sol-gel transitions vary with the length of the nanoribbons. The nanoribbon gels also exhibit red fluorescence and pseudoconductivity values in the same range as current state-of-the-art gels.
Herein, we show that twisted molecular nanoribbons with as many as 322 atoms in the aromatic core are efficient gelators capable of self-assembling into ordered pi-gels with morphologies and sol-gel transitions that vary with the length of the nanoribbon. In addition, the nanoribbon gels show a red fluorescence and also pseudoconductivity values in the same range as current state-of-the-art pi-gels.
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