4.6 Article

Photocatalytic activity of layered MoS2 in the reductive degradation of bromophenol blue

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RSC ADVANCES
卷 12, 期 35, 页码 22465-22475

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra03362c

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  1. FCT-Portuguese Foundation for Science and Technology [UIDB/04565/2020, UIDP/04565/2020, LA/P/0140/2020]
  2. Instituto Superior Tecnico for the Scientific Employment [IST-ID/131/2018]

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In this study, layered MoS2 was produced using a hydrothermal method and characterized in detail. The experimental results showed that MoS2 exhibited excellent catalytic activity in bromophenol blue degradation. The preparation method of MoS2 improved light harvesting, prevented fast charge recombination, and created suitable electron transfer sites for photocatalytic reactions.
Molybdenum disulphide (MoS2) is a layered material with interesting photocatalytic properties. In this study, a layered MoS2 was produced using a hydrothermal method. The obtained material was characterised by XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), SEM (scanning electron microscopy), UV-Vis spectroscopy, DLS (dynamic light scattering), and zeta potential analysis. For the evaluation of the photocatalytic properties of layered MoS2, a solution of bromophenol blue (BPB) and the catalyst was illuminated for 120 minutes. According to the experimental results, MoS2 exhibited excellent catalytic activity in BPB degradation. The MoS2 preparation method enabled improved light harvesting, avoided fast charge recombination (related to bulk MoS2), and created a large number of suitable electron transfer sites for photocatalytic reactions. Simulation of BPB decay and bromide production was carried out for a further understanding of MoS2 photocatalytic action. The simulation results proved the reduction mechanism of BPB photodegradation.

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