☆ 4.8 Review

Cyrene: a bio-based novel and sustainable solvent for organic synthesis

GREEN CHEMISTRY (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Review Chemistry, Multidisciplinary

Green Chemistry in the Synthesis of Pharmaceuticals

Supratik Kar et al.

Summary: The principles of green chemistry can be effectively implemented in the green synthesis of pharmaceuticals by choosing solvent-free or green solvents, considering one-pot synthesis, multicomponent reactions, continuous processing, and process intensification approaches. Researchers and industries are actively pursuing green synthesis processes to control waste reduction and protect the environment.

CHEMICAL REVIEWS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dihydrolevoglucosenone (Cyrene™) as a versatile biobased solvent for lignin fractionation, processing, and chemistry

Antoine Duval et al.

Summary: The solubility of technical lignins depends on their structure and extraction process, with only a few polar aprotic solvents capable of fully dissolving them. This study evaluated Cyrene as an alternative solvent and found it to be effective in fully dissolving KL in Cyrene-water mixtures, as well as suitable for refining and chemically modifying lignins. Cyrene shows promise as a green solvent for lignin fractionation, processing, and chemistry, promoting greener processes when solvents are necessary.

GREEN CHEMISTRY (2022)

添加到收藏夹

Article Biochemistry & Molecular Biology

Biocatalysed reductions of α-ketoesters employing CyreneTM as cosolvent

Gonzalo de Gonzalo

Summary: Cyrene™ is a new polar solvent that has shown beneficial effects on bioreduction conversions in enzyme-catalyzed reactions. Its presence at a certain concentration can improve reaction rates and optical purities of the products.

BIOCATALYSIS AND BIOTRANSFORMATION (2022)

添加到收藏夹

Review Chemistry, Organic

Green solvents for the formation of amide linkages

Debora Procopio et al.

Summary: This review discusses literature from the past decade on strategies for reducing and replacing hazardous solvents, focusing on the use of biobased and neoteric solvents, such as ionic liquids and deep eutectic solvents, as greener alternatives for amide bond formation.

ORGANIC & BIOMOLECULAR CHEMISTRY (2022)

添加到收藏夹

Article Engineering, Chemical

Sustainable fabrication and pervaporation application of bio-based membranes: Combining a polyhydroxyalkanoate (PHA) as biopolymer and Cyrene™ as green solvent

Pacome Tomietto et al.

Summary: This study aims to develop a more sustainable solution for membrane fabrication by investigating a new combination of bio-based materials, including a polyhydroxyalkanoate (PHA) as a polymer and Cyrene(TM) as a solvent for the phase inversion process. Various parameters of the phase inversion process were studied to identify different membrane microstructure possibilities and their final performances, resulting in membranes with different architectures successfully applied in pervaporation for the separation of an organic/organic azeotropic mixture.

JOURNAL OF MEMBRANE SCIENCE (2022)

添加到收藏夹

Article Polymer Science

Ring-Opening Metathesis Polymerization of Unsaturated Carbohydrate Derivatives: Levoglucosenyl Alkyl Ethers

Tapas Debsharma et al.

Summary: Polymerization of biomass-derived levoglucosenyl alkyl ethers using the Grubbs catalyst yields thermoplastic polyacetals with specific thermal properties in various solvents. The initiation step of the polymerization process is slow, with catalyst consumption leading to deactivation of chain ends.

MACROMOLECULES (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cyrene™ as a Neoteric Bio-Based Solvent for Catalyst-Free Microwave-Assisted Construction of Diverse Bipyridine Analogues for Heavy-Metal Sensing

Ramuel John Inductivo Tamargo et al.

Summary: An environmentally friendly synthetic protocol was developed using the bio-renewable solvent Cyrene to access polyfunctionalized bipyridines from readily available amines, chromone-3-carboxaldehydes, and pyridinylacetonitriles. The method is characterized by operational simplicity, short reaction time, high yields, and the synthesized compounds have demonstrated the ability to detect heavy metal ions.

CHEMSUSCHEM (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Polymer Chemistry Applications of Cyrene and its Derivative Cygnet 0.0 as Safer Replacements for Polar Aprotic Solvents

Roxana A. Milescu et al.

Summary: This study investigates the use of a binary solvent system composed of Cyrene and its derivative Cygnet 0.0 in membrane technology and biocatalytic synthesis of polyesters. The results show that Cygnet 0.0 is a promising candidate for the enzymatic synthesis of high molecular weight polyesters, and that Cyrene blends could be viable replacements for toxic polar aprotic solvents in membrane production. New polymeric membranes of different morphology can be manufactured by using Cyrene, Cygnet 0.0, and their blend, depending on the casting solution's temperature and solvent/mixture composition.

CHEMSUSCHEM (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

High yield and greener C-H difluoromethylation reactions using copper iodide nanoparticles/boron nitride nanosheets as a versatile and recyclable heterogeneous catalyst

Udayakumar Veerabagu et al.

Summary: In this study, copper iodide nanoparticles/boron nitride nanosheets were successfully prepared and utilized as heterogeneous catalysts for C-H difluoromethylation reactions. The newly synthesized catalyst showed high versatility in synthesizing diverse substituted heteroarenes and terminal alkynes with moderate to high yields. Furthermore, the catalyst displayed improved activity compared to commercial copper iodide catalysts, with the ability to be easily recovered and recycled multiple times, making it attractive for large-scale organic bioactive compound synthesis.

REACTION CHEMISTRY & ENGINEERING (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A more sustainable isothiocyanate synthesis by amine catalyzed sulfurization of isocyanides with elemental sulfur

R. Nickisch et al.

Summary: A new catalytic reaction method was developed in this study, which can convert isocyanides to isothiocyanates using sulfur and amine bases at low catalytic amounts, achieving high yields. The optimized reaction conditions considered sustainability and the use of environmentally friendly solvents and temperature, with further optimization of column chromatography purification to reduce waste generation.

RSC ADVANCES (2021)

添加到收藏夹

Article Chemistry, Physical

Assessing biocatalysis using dihydrolevoglucosenone (Cyrene™) as versatile bio-based (co)solvent

Nadia Guajardo et al.

MOLECULAR CATALYSIS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Replacement strategies for non-green dipolar aprotic solvents

Feng Gao et al.

GREEN CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Direct comparison of safer or sustainable alternative dipolar aprotic solvents for use in carbon-carbon bond formation

Suwiwat Sangon et al.

REACTION CHEMISTRY & ENGINEERING (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Biomimetic regioselective and high-yielding Cu(i)-catalyzed dimerization of sinapate esters in green solvent Cyrene™: towards sustainable antioxidant and anti-UV ingredients

Matthieu M. Mention et al.

GREEN CHEMISTRY (2020)

添加到收藏夹

Article Biochemistry & Molecular Biology

Cyrene™ is a green alternative to DMSO as a solvent for antibacterial drug discovery against ESKAPE pathogens

Jason E. Camp et al.

RSC MEDICINAL CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Organic

Diastereoselective sulfa-Michael reactions controlled by a biomass-derived chiral auxiliary

Julian Klepp et al.

TETRAHEDRON (2019)

添加到收藏夹

Article Engineering, Chemical

New frontiers in sustainable membrane preparation: Cyrene™ as green bioderived solvent

T. Marino et al.

JOURNAL OF MEMBRANE SCIENCE (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Argentous Deep Eutectic Solvent Approach for Scaling Up the Production of Colloidal Silver Nanocrystals

Laxmi Adhikari et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of amides from acid chlorides and amines in the bio-based solvent Cyrene™

Thomas W. Bousfield et al.

GREEN CHEMISTRY (2019)

添加到收藏夹

Article Polymer Science

Development of bio-acrylic polymers from Cyrene™: transforming a green solvent to a green polymer

Parijat Ray et al.

POLYMER CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic hydrogenation of dihydrolevoglucosenone to levoglucosanol with a hydrotalcite/mixed oxide copper catalyst

Mario De Bruyn et al.

GREEN CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Tuning zirconia-supported metal catalysts for selective one-step hydrogenation of levoglucosenone

Jaime Mazario et al.

GREEN CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Development of pharmaceutically relevant bio-based intermediates though aldol condensation and Claisen-Schmidt reactions of dihydrolevoglucosenone (Cyrene (R))

Liam Hughes et al.

GREEN CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Organic solvent- and catalyst-free Baeyer-Villiger oxidation of levoglucosenone and dihydrolevoglucosenone (Cyrene (R)): a sustainable route to (S)-gamma-hydroxymethyl-alpha,beta-butenolide and (S)-gamma-hydroxymethyl-gamma-butyrolactone

Guillaume Bonneau et al.

GREEN CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Towards sustainable kinetic resolution, a combination of bio-catalysis, flow chemistry and bio-based solvents

Andree Iemhoff et al.

GREEN CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Organic

Cyrene as a bio-based solvent for HATU mediated amide coupling

Kirsty L. Wilson et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Organic

Synthesis of a Chiral Auxiliary Family from Levoglucosenone and Evaluation in the Diels-Alder Reaction

Julian Klepp et al.

SYNLETT (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Bio-available Solvent Cyrene: Synthesis, Derivatization, and Applications

Jason E. Camp

CHEMSUSCHEM (2018)

添加到收藏夹

Editorial Material Chemistry, Multidisciplinary

Catalyst: Possible Consequences of the N-Methyl Pyrrolidone REACH Restriction

James Sherwood et al.

CHEM (2018)

添加到收藏夹

Article Chemistry, Organic

One-pot synthesis of carbohydrate exo-cyclic enones and hemiketals with 6,8-dioxabicyclo-[3.2.1]octane moieties. Serendipitous formation of a spironolactone when 2-pyridinecarboxaldehyde is used as the reactant. Part II

Rachael E. Hohol et al.

TETRAHEDRON (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Sustainable production of highly conductive multilayer graphene ink for wireless connectivity and IoT applications

Kewen Pan et al.

NATURE COMMUNICATIONS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enzymatic reduction of levoglucosenone by an alkene reductase (OYE 2.6): a sustainable metal- and dihydrogen-free access to the bio-based solvent Cyrene®

Louis M. M. Mouterde et al.

GREEN CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Production of Levoglucosenone and Dihydrolevoglucosenone by Catalytic Reforming of Volatiles from Cellulose Pyrolysis Using Supported Ionic Liquid Phase

Shinji Kudo et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Greener solvents for solid-phase synthesis

Stefan Lawrenson et al.

GREEN CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of ureas in the bio-alternative solvent Cyrene

Liam Mistry et al.

GREEN CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Hydrogenation of levoglucosenone to renewable chemicals

Siddarth H. Krishna et al.

GREEN CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Identification of high performance solvents for the sustainable processing of graphene

H. J. Salavagione et al.

GREEN CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Organic

Structure-reactivity correlations of the abnormal Beckmann reaction of dihydrolevoglucosenone oxime

Amani Alhifthi et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Organic

Concise and efficient synthesis of E-stereoisomers of exo-cyclic carbohydrate enones. Aldol condensation of dihydrolevoglucosenone with five-membered aromatic aldehydes1 Part 1

Zbigniew J. Witczak et al.

TETRAHEDRON LETTERS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Environmentally benign and diastereoselective synthesis of 2,4,5-trisubstituted-2-imidazolines

Hai Anh Le Phuong et al.

RSC ADVANCES (2017)

添加到收藏夹

Article Chemistry, Organic

Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation

Kirsty L. Wilson et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of cholesterol-reducing sterol esters by enzymatic catalysis in bio-based solvents or solvent-free

Adrienne Gallant Lanctot et al.

RSC ADVANCES (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dihydrolevoglucosenone (Cyrene) As a Green Alternative to N,N-Dimethylformamide (DMF) in MOF Synthesis

Jinfeng Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Optimization of the Laccase-Catalyzed Synthesis of (±)-Syringaresinol and Study of its Thermal and Antiradical Activities

Abdus S. Jaufurally et al.

CHEMISTRYSELECT (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dihydrolevoglucosenone (Cyrene) as a bio-based alternative for dipolar aprotic solvents

James Sherwood et al.

CHEMICAL COMMUNICATIONS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic Fast Pyrolysis of Cellulose to Prepare Levoglucosenone Using Sulfated Zirconia

Zhi Wang et al.

CHEMSUSCHEM (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

A green and rapid approach for the stereoselective vinylation of phenol, thiol and amine derivatives in water

Yaghoub Sarrafi et al.

GREEN CHEMISTRY (2011)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.