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Organic-inorganic hybrid cathode interlayer materials for efficient organic solar cells

SUSTAINABLE ENERGY & FUELS (2022)

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Review Polymer Science

Recent advances of organometallic complexes in emerging photovoltaics

Huaizhi Gao et al.

Summary: Organometallic complexes (OMCs) with organic and metal active moieties show great potential in solar cells, providing diverse structures and unique charge centers for improved performance. They can be used as active or interlayer materials in various solar cell systems, using some metals as dopants to enhance photoelectric performance. Opportunities and challenges of OMCs in solar cell applications are discussed.

JOURNAL OF POLYMER SCIENCE (2022)

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Article Chemistry, Physical

Quantum Efficiency and Voltage Losses in P3HT:Non-fullerene Solar Cells

Xiaoyun Xu et al.

Summary: Poly(3-hexylthiophene) (P3HT) is a promising donor material in organic photovoltaics, especially for efficient indoor light harvesting. However, the power conversion efficiency of P3HT-based solar cells is limited due to significant voltage losses. In this study, the origin of high quantum efficiency and voltage losses in P3HT:non-fullerene solar cells was identified, and a strategy to reduce the losses was proposed. The findings suggest that improving the performance of P3HT-based solar cells requires increasing the donor-acceptor interface distance.

ACTA PHYSICO-CHIMICA SINICA (2022)

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Article Chemistry, Multidisciplinary

Fluidic Manipulating of Printable Zinc Oxide for Flexible Organic Solar Cells

Xiaoyu Liu et al.

Summary: A new method has been developed to manipulate the fluidics of sol-gel ZnO precursor and optimize processability of ZnO layer for flexible OSCs by changing Lewis base. This method results in high-quality ZnO layers suitable for flexible OSCs with improved photostability, achieving a power conversion efficiency of 16.71%, the best value reported so far.

ADVANCED MATERIALS (2022)

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Article Materials Science, Multidisciplinary

TiO2 nanoparticles via simple surface modification as cathode interlayer for efficient organic solar cells

Xing Chen et al.

Summary: By surface modification of TiO2 nanoparticles to reduce aggregation and form smooth TiO2-N film, the power conversion efficiency of PM6:BTP-4Cl solar cells was improved.

ORGANIC ELECTRONICS (2022)

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Review Chemistry, Multidisciplinary

Recent progress in organic solar cells (Part I material science)

Yahui Liu et al.

Summary: In recent years, organic solar cells (OSCs) have made significant progress with power conversion efficiencies (PCEs) over 18%, showing promising practical applications. Key research focuses in the OSC field include development in material science and interface materials. The article systematically summarizes the recent progress in these areas and discusses current challenges and future developments.

SCIENCE CHINA-CHEMISTRY (2022)

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Article Materials Science, Multidisciplinary

Coordination-Induced Defects Elimination of SnO2 Nanoparticles via a Small Electrolyte Molecule for High-Performance Inverted Organic Solar Cells

Huaizhi Gao et al.

Summary: Doping electrolyte PAS into SnO2 films can reduce surface defects and enhance the performance of inverted organic solar cells (OSCs). PAS doping lowers the surface energy and improves the distribution of the active layer, leading to better exciton dissociation and charge transport.

ADVANCED OPTICAL MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Amino acid functionalised perylene bisimides for aqueous solution-deposited electron transporting interlayers in organic photovoltaic devices

Joseph Cameron et al.

Summary: The development of solution-processable electron transport layers that are suitable for orthogonal processing is crucial for the feasibility of solution-processed organic photovoltaic devices. In this study, a series of amino acid appended perylene bisimides (PBIs) were used as electron transporting interlayers in P3HT/PC61BM based organic photovoltaic cells. These PBIs are easily soluble in water at high pH and can be processed as solutions. The performance of the solar cells varied significantly among the PBIs due to differences in their absorbance, morphology, and photoconductivity properties.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

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Article Chemistry, Multidisciplinary

Single-Junction Organic Solar Cells with 19.17% Efficiency Enabled by Introducing One Asymmetric Guest Acceptor

Rui Sun et al.

Summary: The ternary strategy is an effective approach to achieve high-efficiency OSCs, but the nonradiative voltage loss limits further efficiency improvements. By incorporating an asymmetric guest acceptor BTP-2F2Cl, the OSCs show improved photoluminescence quantum yield, exciton diffusion length, and absorption spectrum, leading to enhanced power conversion efficiency.

ADVANCED MATERIALS (2022)

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Article Chemistry, Multidisciplinary

A benzo[ghi]-perylene triimide based double-cable conjugated polymer for single-component organic solar cells

Dan Wang et al.

Summary: Single-component organic solar cells with high stability and simplified fabrication process still need improvement in terms of photo-active materials and photovoltaic performance. In this work, a new double-cable polymer PBTT-BPTI was constructed to enhance power conversion efficiencies through the introduction of fused core TTDO into the main backbone and BPTI unit into the side chain.

CHINESE CHEMICAL LETTERS (2022)

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Article Chemistry, Physical

Single-junction organic solar cells with over 19% efficiency enabled by a refined double-fibril network morphology

Lei Zhu et al.

Summary: Morphological control of donor and acceptor domains is crucial for efficient organic photovoltaics, and this study demonstrates a double-fibril network strategy to achieve a high power conversion efficiency of 19.3%.

NATURE MATERIALS (2022)

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Article Multidisciplinary Sciences

Organometallic-functionalized interfaces for highly efficient inverted perovskite solar cells

Zhen Li et al.

Summary: Functionalizing the interfaces of multication and halide perovskite solar cells with an organometallic compound, ferrocenyl-bis-thiophene-2-carboxylate (FcTc(2)), enhances their efficiency and stability. The resulting devices exhibit high performance and stability, as demonstrated by tests and continuous operation.

SCIENCE (2022)

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Article Energy & Fuels

An alcohol-dispersed conducting polymer complex for fully printable organic solar cells with improved stability

Youyu Jiang et al.

Summary: Researchers have developed an alcohol-dispersed PEDOT formulation for efficient and stable organic solar cells. The formulation shows good wetting properties and low acidity, avoiding the drawbacks of aqueous PEDOT:PSS. Organic photovoltaics based on PEDOT:F achieved a power conversion efficiency of 15% and retained 83% of the initial efficiency after 1,330 hours of continuous illumination.

NATURE ENERGY (2022)

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Article Chemistry, Multidisciplinary

The Energy Level Conundrum of Organic Semiconductors in Solar Cells

Jules Bertrandie et al.

Summary: The study investigates the energy levels of 33 organic semiconductors using multiple techniques and explores their impact on the performance of solar cells. The findings reveal that high-performing systems have significant ionization energy offsets, and vanishing ionization energy offsets are detrimental to device performance.

ADVANCED MATERIALS (2022)

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Article Chemistry, Physical

Self-Assembly Metal Chelate as Ultraviolet Filterable Interface Layer for Efficient Organic Solar Cells

Runnan Yu et al.

Summary: Interface engineering is crucial for improving the efficiency and stability of organic solar cells (OSCs). In this study, a self-assembly metal chelate is used as both an interfacial modification layer and a UV-light filter, resulting in higher efficiency and stability of the OSCs.

ADVANCED ENERGY MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Manipulating the D:A interfacial energetics and intermolecular packing for 19.2% efficiency organic photovoltaics

Chengliang He et al.

Summary: Manipulating the donor:acceptor energetics is crucial for achieving balanced charge separation and recombination in organic solar cells (OSCs). In this study, a non-fullerene electron acceptor, BTP-H2, was designed and synthesized to pair with the polymer donor PM6, showing strong intermolecular interaction and near-zero highest occupied molecular orbital (HOMO) offset. The results demonstrated efficient charge separation and optimized energy conversion, leading to high-performance OSCs with a power conversion efficiency (PCE) of 18.5% and a peak photon-to-electron response of approximately 90%.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

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Article Chemistry, Multidisciplinary

On the interface reactions and stability of nonfullerene organic solar cells

Pei Jiang et al.

Summary: This article focuses on the interface stability of organic solar cells (OSCs) and discusses the interfacial reactions, mechanisms, and strategies to suppress them. The reactivity of the C=C vinyl linker is identified as a weak point for interface stability, which can be enhanced by reducing its reactivity, removing it, modifying the surface of interfacial layers, or developing novel interfacial materials.

CHEMICAL SCIENCE (2022)

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Article Materials Science, Multidisciplinary

Healing the degradable organic-inorganic heterointerface for highly efficient and stable organic solar cells

Yangdan Tao et al.

Summary: In this study, an effective interfacial strategy was developed to enhance the chemical, electric, and electronic properties of the organic-inorganic heterointerface. The results showed that this approach improved the performance of organic solar cells and exhibited thickness-insensitive features.

INFOMAT (2022)

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Article Chemistry, Multidisciplinary

An Organic-Inorganic Hybrid Electrolyte as a Cathode Interlayer for Efficient Organic Solar Cells

Chaowei Zhao et al.

Summary: The hybrid electrolyte based on a cyclic Ti-oxo cluster and organic ammonium bromide salt demonstrates excellent solubility, aligned work function, good conductivity, and amorphous state, making it suitable for application as a cathode interlayer in organic solar cells with a high power conversion efficiency. This work suggests that hybrid electrolytes could be a new kind of semiconductor with promising applications in organic electronics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Manipulation of Zinc Oxide with Zirconium Doping for Efficient Inverted Organic Solar Cells

Xin Song et al.

Summary: By doping zirconium (Zr) into zinc oxide (ZnO) layers, it is possible to increase light transmittance, optimize surface morphology, enhance charge extraction performance, and reduce charge recombination probability, thereby significantly improving the efficiency and performance of organic solar cells.

SMALL (2021)

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Article Chemistry, Physical

Significant Enhancement of Illumination Stability of Nonfullerene Organic Solar Cells via an Aqueous Polyethylenimine Modification

Lu Hu et al.

Summary: The modification of ZnO surface with aqueous polyethylenimine (a-PEI) has been shown to significantly enhance the stability of nonfullerene (NF) organic solar cells, reducing surface defects and preventing decomposition of NF acceptors under illumination while improving device performance.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

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Article Nanoscience & Nanotechnology

Molecular Doping Inhibits Charge Trapping in Low-Temperature-Processed ZnO toward Flexible Organic Solar Cells

Yiqiu Xia et al.

Summary: Improvements in the electronic quality of the ZnO interlayer were achieved by doping TPT-S, leading to enhanced electron transport capability and reduced charge recombination. The doping of TPT-S significantly inhibited unfavorable charge trapping/detrapping process in low-temperature-processed devices. OSCs using ZnO:TPT-S as the cathode interlayer demonstrated high efficiencies on both flexible and rigid substrates.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

An Efficiency of 16.46% and a T80 Lifetime of Over 4000 h for the PM6:Y6 Inverted Organic Solar Cells Enabled by Surface Acid Treatment of the Zinc Oxide Electron Transporting Layer

Yunfei Han et al.

Summary: The surface pH conditions of solution-processed ZnO films were found to be closely related to the performance and stability of NFA OSCs. Treating ZnO films with acid solutions improved device performance, while removal of surface -OH groups alleviated performance issues and improved stability. Acid solutions, particularly PET treatment, were effective in enhancing performance, leading to long-term stability of the heterojunction solar cell.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Inorganic & Nuclear

Heteroleptic Ruthenium(II) Complexes with 2,2′-Bipyridines Having Carbonitriles as Anchoring Groups for ZnO Surfaces: Syntheses, Physicochemical Properties, and Applications in Organic Solar Cells

Fernando F. Salomon et al.

Summary: Heteroleptic ruthenium (II) complexes were used as sensitizers in organic solar cells to enhance photo-conversion efficiency and stability. The properties of the complexes were tuned by changing substituents, leading to improvements in spectroscopic, photophysical, and electrochemical characteristics. By attaching these complexes to ZnO as an interfacial layer, enhancements in OSC performance were achieved through suppression of degradative reactions and increased stability.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Mechanism of the Alcohol-Soluble Ionic Organic Interlayer in Organic Solar Cells

Chuang Feng et al.

Summary: This study investigates the adsorption behavior and working mechanism of alcohol-soluble ionic organic interlayer on different electrode substrates through a combination of experimental measurements and density functional theory calculations. The results reveal different adsorption mechanisms when the ionic organic bipyridine salt interlayer is adsorbed on Ag and ITO surfaces, providing important insights for understanding and improving the performance of organic electronic devices.

LANGMUIR (2021)

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Article Chemistry, Physical

High-Efficiency and Stable Organic Solar Cells with Stacked LiF and Organic Electrolytes as Cathode Interface Layers

Jingpeng Ren et al.

Summary: The addition of lithium fluoride as a double electron transport layer in organic solar cells effectively reduces the work function of the active layer, improves electron injection efficiency, promotes charge extraction and collection, and enhances the stability and efficiency of the device.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Ti-Oxo Clusters with Peripheral Alkyl Groups as Cathode Interlayers for Efficient Organic Solar Cells

Xing Chen et al.

Summary: Three independent Ti-oxo clusters with precise chemical structures are developed as cathode interlayers in OSCs, providing high power conversion efficiency. These TOCs have excellent solubility, well-aligned work function, and can easily form smooth films.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Nanographene-Osmapentalyne Complexes as a Cathode Interlayer in Organic Solar Cells Enhance Efficiency over 18%

Longzhu Liu et al.

Summary: Interface engineering through conjugated extension of metal-nanographene molecules as cathode interlayer materials has successfully enhanced the photovoltaic performance of nonfullerene solar cells. Modified hexabenzocoronenes-styryl can effectively improve the performance of organic solar cells by facilitating carrier transport and impeding carrier recombination through better interfacial contacts and morphology regulation.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Silicon Naphthalocyanine Tetraimides: Cathode Interlayer Materials for Highly Efficient Organic Solar Cells

Chunsheng Cai et al.

Summary: Naphthalocyanine derivatives (SiNcTI-N and SiNcTI-Br) were used as cathode interlayer materials (CIMs) in organic solar cells for the first time, showing excellent performance. Among them, SiNcTI-Br CIM exhibited high conductivity and electron mobility, effectively enhancing the efficiency of PM6:Y6-based OSCs.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Size-Controllable Metal Chelates as Both Light Scattering Centers and Electron Collection Layer for High-Performance Polymer Solar Cells

Hao Liu et al.

CCS Chemistry (2021)

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Article Chemistry, Physical

A Nonionic Alcohol Soluble Polymer Cathode Interlayer Enables Efficient Organic and Perovskite Solar Cells

Anirudh Sharma et al.

Summary: The study introduces a new efficient CIL based on a naphthalene diimide core and oligo (ethylene glycol) side-chain conjugated polymer, which demonstrates good thermal stability and ease of processing, leading to improved photovoltaic parameters, reduced carrier recombination, and enhanced device performance.

CHEMISTRY OF MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Enhanced Charge Collection in Non-Fullerene Organic Solar Cells Using Iridium Complex as an Electron Extraction Layer

Pengchao Zhou et al.

Summary: The use of ultrathin iridium complexes as electron extraction layers has been shown to improve the performance of non-fullerene organic photovoltaic devices, with optimized bilayer EELs achieving significantly higher power conversion efficiency. The universality of iridium complexes when combined with other materials as EELs may offer a promising direction for further enhancing the performance of OPVs.

ADVANCED MATERIALS INTERFACES (2021)

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Article Chemistry, Physical

Reduced non-radiative charge recombination enables organic photovoltaic cell approaching 19% efficiency

Pengqing Bi et al.

Summary: Introducing HDO-4Cl increased the exciton diffusion length in the acceptor phase, reducing non-radiative charge recombination and improving photon utilization efficiency in PBDB-TF: eC9-based OPV cells. This led to achieving a high-efficiency OPV cell with outstanding power conversion efficiency, demonstrating the effectiveness of regulating exciton behaviors in reducing energy loss.

JOULE (2021)

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Article Materials Science, Multidisciplinary

Adenine-based polymer modified zinc oxide for efficient inverted organic solar cells

Yi Wang et al.

Summary: In this research, a polymer based on the nucleobase adenine was synthesized and found to effectively modify zinc oxide nanoparticle films, improving conductivity and device performance. Modification of the zinc oxide nanoparticle interlayer with the polymer efficiently suppressed charge recombination and enhanced the efficiency of solar cells.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Multidisciplinary

Natural biomaterial sarcosine as an interfacial layer enables inverted organic solar cells to exhibit over 16.4% efficiency

Mei Liu et al.

Summary: Sarcosine as an ETL successfully improved the performance of inverted organic solar cells by reducing the work function and increasing surface energy of ITO or ITO/ZnO, optimizing the morphology and molecular arrangement of the active layers, promoting charge transport and collection, and ultimately enhancing the power conversion efficiency.

NANOSCALE (2021)

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Review Materials Science, Multidisciplinary

Cluster-assembled materials: Ordered structures with advanced properties

Qingda Liu et al.

Summary: Cluster-assembled materials (CAMs) exhibit delicate structures with tailored properties, strongly dependent on the structure and coordination state of cluster building blocks. CAMs often display well-organized structures at the subnanometer scale, with application potentials lying in the cluster arrangements and interactions at this level.

INFOMAT (2021)

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Review Chemistry, Multidisciplinary

Stability: next focus in organic solar cells based on non-fullerene acceptors

Yawen Li et al.

Summary: This study systematically discusses the degradation mechanisms and stability issues of NFA-OSCs, presents strategies to improve stability, and suggests that stability should be the next focus in the field of NFA-OSCs.

MATERIALS CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Physical

Induced crystallization of sol-gel-derived zinc oxide for efficient non-fullerene polymer solar cells†

Jiaxin Zheng et al.

Summary: By introducing in situ induced crystallization of zinc oxide (ic-ZnO), the crystallinity of zinc oxide is increased, effectively reducing interfacial charge recombination in PSCs, leading to improved device performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Materials Science, Multidisciplinary

Highly efficient organic solar cells enabled by a porous ZnO/PEIE electron transport layer with enhanced light trapping

Shenya Qu et al.

Summary: A porous inorganic/organic hybrid material P-ZnO has been developed and adopted in inverted organic solar cells, showing improved device performance with enhanced light trapping and long-term stability. The universality of P-ZnO as the electron transport layer has been verified on three different photovoltaic systems. Significant enhancements in power conversion efficiency and long-term stability have been achieved, demonstrating the great potential of PZnO as ETL for high-performance and air-stable OSCs.

SCIENCE CHINA-MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Interlayers for non-fullerene based polymer solar cells: distinctive features and challenges

Roberto Sorrentino et al.

Summary: Polymer solar cells based on non-fullerene acceptors have achieved high power conversion efficiencies recently. Interlayers play a key role in charge collection and device stability, but the mechanisms are not fully understood yet.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Recent progress of thin-film photovoltaics for indoor application

Nanfu Yan et al.

CHINESE CHEMICAL LETTERS (2020)

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Interface-enhanced organic solar cells with extrapolated T80 lifetimes of over 20 years

Xiang Xu et al.

SCIENCE BULLETIN (2020)

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Enhanced Organic and Perovskite Solar Cell Performance through Modification of the Electron-Selective Contact with a Bodipy-Porphyrin Dyad

Konstantina Gkini et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Materials Science, Multidisciplinary

Efficiency enhancement of organic solar cells enabled by interface engineering of sol-gel zinc oxide with an oxadiazole-based material

Billy Fanady et al.

ORGANIC ELECTRONICS (2020)

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Article Nanoscience & Nanotechnology

Suppressing the Photocatalytic Activity of Zinc Oxide Electron-Transport Layer in Nonfullerene Organic Solar Cells with a Pyrene-Bodipy Interlayer

Anastasia Soultati et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Multidisciplinary Sciences

Cathode engineering with perylene-diimide interlayer enabling over 17% efficiency single-junction organic solar cells

Jia Yao et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

A Cost-Effective, Aqueous-Solution-Processed Cathode Interlayer Based on Organosilica Nanodots for Highly Efficient and Stable Organic Solar Cells

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ADVANCED MATERIALS (2020)

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Review Chemistry, Physical

Inorganic and Hybrid Interfacial Materials for Organic and Perovskite Solar Cells

Leonidas C. Palilis et al.

ADVANCED ENERGY MATERIALS (2020)

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Interfacial Dipole in Organic and Perovskite Solar Cells

Qi Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Robust metal ion-chelated polymer interfacial layer for ultraflexible non-fullerene organic solar cells

Fei Qin et al.

NATURE COMMUNICATIONS (2020)

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Article Materials Science, Multidisciplinary

Sn-N/Sn-O interaction improving electron collection in non-fullerene organic solar cells

Lu Hu et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Review Chemistry, Multidisciplinary

Molecular materials as interfacial layers and additives in perovskite solar cells

Maria Vasilopoulou et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Novel cathode buffer layer of Al(acac)3enables efficient, large area and stable semi-transparent organic solar cells

Yiming Bai et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Physical

Increased Electron Transport and Hole Blocking in an Aqueous Solution Processed Dye-Doped ZnO Cathode Interlayer for High Performance Organic Solar Cells

Yinqi Luo et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

A universal solution processed interfacial bilayer enabling ohmic contact in organic and hybrid optoelectronic devices

Joel Troughton et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Materials Science, Multidisciplinary

Surface modification of ZnO electron transport layers with glycine for efficient inverted non-fullerene polymer solar cells

Xiaoqian Zhu et al.

ORGANIC ELECTRONICS (2019)

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Article Materials Science, Multidisciplinary

Passivating ZnO with a naphthalimide-Schiff base as electron transport layer for inverted polymer solar cells

Zhixiang Gao et al.

ORGANIC ELECTRONICS (2019)

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Article Chemistry, Multidisciplinary

Tetrahydroxy-Perylene Bisimide Embedded in Zinc Oxide Thin Film as Electron Transporting Layer for High Performance Non-Fullerene Organic Solar Cells

Xinbo Wen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Materials Science, Multidisciplinary

Polymer solar cells based on spontaneously-spreading film with double electron-transporting layers

Hao Lu et al.

ORGANIC ELECTRONICS (2019)

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Article Materials Science, Multidisciplinary

Self-Assembled Monomolecular Layer Modified ZnO for Efficient Inverted Polymer Solar Cells with 11.53% Efficiency

Guanshui Xie et al.

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS (2019)

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Article Nanoscience & Nanotechnology

Enhanced Electron Transportation by Dye Doping in Very Low-Temperature (<130 °C)-Processed Sol-Gel ZnO toward Flexible Organic Solar Cells

Xinbo Wen et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Nanoscience & Nanotechnology

New Antimony-Based Organic-Inorganic Hybrid Material as Electron Extraction Layer for Efficient and Stable Polymer Solar Cells

Donia Fredj et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Lithium-Ion-Based Conjugated Polyelectrolyte as an Interface Material for Efficient and Stable Non-Fullerene Organic Solar Cells

Junli Li et al.

CHEMSUSCHEM (2019)

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Article Chemistry, Multidisciplinary

Efficient organic-inorganic hybrid cathode interfacial layer enabled by polymeric dopant and its application in large-area polymer solar cells

Sheng Dong et al.

SCIENCE CHINA-CHEMISTRY (2019)

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Article Materials Science, Multidisciplinary

Solution-processable ZnO/3-aminopropyltriethoxysilane hybrid cathode interlayer for non-fullerene organic solar cells

Ming Zhou et al.

THIN SOLID FILMS (2019)

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Review Chemistry, Multidisciplinary

Polyoxometalates in dye-sensitized solar cells

Li Chen et al.

CHEMICAL SOCIETY REVIEWS (2019)

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A Printable Organic Cathode Interlayer Enables over 13% Efficiency for 1-cm2 Organic Solar Cells

Qian Kang et al.

JOULE (2019)

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Fabrication and Characterization of Hybrid Organic-Inorganic Electron Extraction Layers for Polymer Solar Cells toward Improved Processing Robustness and Air Stability

Donia Fredj et al.

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Construction of Layered Structure of Anion-Cations To Tune the Work Function of Aluminum-Doped Zinc Oxide for Inverted Polymer Solar Cells

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Engineering of Porphyrin Molecules for Use as Effective Cathode Interfacial Modifiers in Organic Solar Cells of Enhanced Efficiency and Stability

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Silane-Capped ZnO Nanoparticles for Use as the Electron Transport Layer in Inverted Organic Solar Cells

Junfeng Wei et al.

ACS NANO (2018)

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Reinforcing the Built-In Field for Efficient Charge Collection in Polymer Solar Cells

Jong-Hoon Lee et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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A green route to a novel hyperbranched electrolyte interlayer for nonfullerene polymer solar cells with over 11% efficiency

Dan Zhou et al.

CHEMICAL COMMUNICATIONS (2018)

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Review Chemistry, Multidisciplinary

Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters

Wei-Hui Fang et al.

CHEMICAL SOCIETY REVIEWS (2018)

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Article Energy & Fuels

Efficient Polymer Solar Cells with Alcohol-Soluble Zirconium(IV) Isopropoxide Cathode Buffer Layer

Zhen Luo et al.

ENERGIES (2018)

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Efficient organic solar cells employing ytterbium ion-doped zinc oxide as cathode transporting layer

Zhen-Zhen Gui et al.

ORGANIC ELECTRONICS (2018)

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Article Materials Science, Multidisciplinary

Erbium (III) tris(8-hydroxyquinoline) doped zinc oxide interfacial layer for improved performance of polymer solar cells

B. Hari Babu et al.

ORGANIC ELECTRONICS (2018)

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Article Chemistry, Physical

Synergy of a titanium chelate electron collection layer and a vertical phase separated photoactive layer for efficient inverted polymer solar cells

Yiming Bai et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

Tellurophene-based metal-organic framework nanosheets for high-performance organic solar cells

Wang Xing et al.

JOURNAL OF POWER SOURCES (2018)

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Article Chemistry, Physical

High-efficiency polymer solar cells with low temperature solution-processed SnO2/PFN as a dual-function electron transporting layer

Ping Shen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Energy & Fuels

Tris(8-hydroxyquinoline)aluminum(III)-Cored Molecular Cathode Interlayer: Improving Electron Mobility and Photovoltaic Efficiency of Polymer Solar Cells

Zuojia Li et al.

SOLAR RRL (2018)

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Article Chemistry, Organic

Construction of J-type aggregates as multi-functional interlayers for nonfullerene polymer solar cells

Minming Wu et al.

ORGANIC CHEMISTRY FRONTIERS (2018)

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Article Chemistry, Multidisciplinary

Role of Central Metal Ions in 8-Hydroxyquinoline-Doped ZnO Interfacial Layers for Improving the Performance of Polymer Solar Cells

B. Hari Babu et al.

ADVANCED MATERIALS INTERFACES (2018)

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Article Energy & Fuels

Organic Electrolytes Doped ZnO Layer as the Electron Transport Layer for Bulk Heterojunction Polymer Solar Cells

Youn Hwan Kim et al.

SOLAR RRL (2018)

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Article Chemistry, Multidisciplinary

Light-Soaking-Free Inverted Polymer Solar Cells with an Efficiency of 10.5% by Compositional and Surface Modifications to a Low-Temperature-Processed TiO2 Electron-Transport Layer

Yu Yan et al.

ADVANCED MATERIALS (2017)

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Article Chemistry, Physical

Investigating Working Mechanism of Metallophthalocyanine Derivatives as a Cathode Interlayer in Polymer Solar Cells by Photoemission Spectroscopy

Chengzhuo Yu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

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Article Chemistry, Multidisciplinary

Self-assembled diblock conjugated polyelectrolytes as electron transport layers for organic photovoltaics

Dan Zhou et al.

RSC ADVANCES (2017)

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Article Chemistry, Physical

Effect of alkyl chain length of the ammonium groups in SEPC-CIL on the performance of polymer solar cells

Youchun Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Nanoscience & Nanotechnology

Annealing-Free ZnO:PEI Composite Cathode Interfacial Layer for Efficient Organic Solar Cells

Chunyu Liu et al.

ACS PHOTONICS (2017)

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Article Nanoscience & Nanotechnology

Alcohol-Soluble Isoindigo Derivative IIDTh-NSB as a Novel Modifier of ZnO in Inverted Polymer Solar Cells

Biao Guo et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

Low Work Function Lacunary Polyoxometalates as Electron Transport Interlayers for Inverted Polymer Solar Cells of Improved Efficiency and Stability

Marinos Tountas et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Chemistry, Multidisciplinary

A Green Route to Conjugated Polyelectrolyte Interlayers for High-Performance Solar Cells

Jegadesan Subbiah et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Article Chemistry, Physical

Fullerene-Free Organic Solar Cells with Efficiency Over 12% Based on EDTA-ZnO Hybrid Cathode Interlayer

Xiaodong Li et al.

CHEMISTRY OF MATERIALS (2017)

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Review Chemistry, Multidisciplinary

Colloidal metal oxide nanocrystals as charge transporting layers for solution-processed light-emitting diodes and solar cells

Xiaoyong Liang et al.

CHEMICAL SOCIETY REVIEWS (2017)

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Article Nanoscience & Nanotechnology

High-Performance Polymer Solar Cells with Zinc Sulfide-Phenanthroline Derivatives as the Hybrid Cathode Interlayers

Yulei Wu et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Nanoscience & Nanotechnology

High-Performance Inverted Polymer Solar Cells with Zirconium Acetylacetonate Buffer Layers

Haijun Fan et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Nanoscience & Nanotechnology

Solution-Processed 8-Hydroquinolatolithium as Effective Cathode Interlayer for High-Performance Polymer Solar Cells

Wenqing Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Chemistry, Multidisciplinary

Water-Soluble Lacunary Polyoxometalates with Excellent Electron Mobilities and Hole Blocking Capabilities for High Efficiency Fluorescent and Phosphorescent Organic Light Emitting Diodes

Marinos Tountas et al.

ADVANCED FUNCTIONAL MATERIALS (2016)

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Article Chemistry, Multidisciplinary

Surface Structure Modification of ZnO and the Impact on Electronic Properties

Robert M. Hewlett et al.

ADVANCED MATERIALS (2016)

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Article Chemistry, Multidisciplinary

Aqueous Solution Processed Photoconductive Cathode Interlayer for High Performance Polymer Solar Cells with Thick Interlayer and Thick Active Layer

Li Nian et al.

ADVANCED MATERIALS (2016)

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Article Chemistry, Multidisciplinary

n-Type Water/Alcohol-Soluble Naphthalene Diimide-Based Conjugated Polymers for High-Performance Polymer Solar Cells

Zhihong Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Physical

Insights into the working mechanism of cathode interlayers in polymer solar cells via [(C8H17)4N]4[SiW12O40]

Youchun Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Chemistry, Physical

CdS-phenanthroline derivative hybrid cathode interlayers for high performance inverted organic solar cells

Xiaohui Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Chemistry, Physical

High performance polymer solar cells employing a low-temperature solution-processed organic-inorganic hybrid electron transport layer

Woosung Lee et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Materials Science, Multidisciplinary

An organic-inorganic hybrid interlayer for improved electron extraction in inverted polymer solar cells

Eui Jin Lee et al.

JOURNAL OF MATERIALS CHEMISTRY C (2016)

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Article Nanoscience & Nanotechnology

Polyethylenimine Interfacial Layers in Inverted Organic Photovoltaic Devices: Effects of Ethoxylation and Molecular Weight on Efficiency and Temporal Stability

Brett A. E. Courtright et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Review Chemistry, Multidisciplinary

Solution-processable metal oxides/chelates as electrode buffer layers for efficient and stable polymer solar cells

Fuzhi Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

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Review Chemistry, Multidisciplinary

Recent progress and perspective in solution-processed Interfacial materials for efficient and stable polymer and organometal perovskite solar cells

Chu-Chen Chueh et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

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Article Chemistry, Multidisciplinary

Photoconductive Cathode Inter layer for Highly Efficient Inverted Polymer Solar Cells

Li Nian et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Article Multidisciplinary Sciences

Inverted polymer fullerene solar cells exceeding 10% efficiency with poly(2-ethyl-2-oxazoline) nanodots on electron-collecting buffer layers

Sungho Nam et al.

NATURE COMMUNICATIONS (2015)

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Article Nanoscience & Nanotechnology

Improving Efficiency by Hybrid TiO2 Nanorods with 1,10-Phenanthroline as A Cathode Buffer Layer for Inverted Organic Solar Cells

Chunming Sun et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Article Nanoscience & Nanotechnology

Solvents Induced ZnO Nanoparticles Aggregation Associated with Their Interfacial Effect on Organic Solar Cells

Pandeng Li et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Article Chemistry, Multidisciplinary

Lending Triarylphosphine Oxide to Phenanthroline: a Facile Approach to High-Performance Organic Small-Molecule Cathode Interfacial Material for Organic Photovoltaics utilizing Air-Stable Cathodes

Wan-Yi Tan et al.

ADVANCED FUNCTIONAL MATERIALS (2014)

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Article Chemistry, Multidisciplinary

Perylene diimides: a thickness-insensitive cathode interlayer for high performance polymer solar cells

Zhi-Guo Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Article Chemistry, Multidisciplinary

Highly efficient inverted polymer solar cells using fullerene derivative modified TiO2 nanorods as the buffer layer

Chunming Sun et al.

RSC ADVANCES (2014)

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Article Chemistry, Physical

Air-processed inverted organic solar cells utilizing a 2-aminoethanol-stabilized ZnO nanoparticle electron transport layer that requires no thermal annealing

Il Jeon et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Chemistry, Physical

High efficiency inverted polymer solar cells with room-temperature titanium oxide/polyethylenimine films as electron transport layers

Dong Yang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Chemistry, Physical

A water-soluble metallophthalocyanine derivative as a cathode interlayer for highly efficient polymer solar cells

Xiao Cheng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Article Nanoscience & Nanotechnology

Solution-Processed Hybrid Cathode Interlayer for Inverted Organic Solar Cells

Yulei Wu et al.

ACS APPLIED MATERIALS & INTERFACES (2013)

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Review Chemistry, Multidisciplinary

Recent advances in water/alcohol-soluble π-conjugated materials: new materials and growing applications in solar cells

Chunhui Duan et al.

CHEMICAL SOCIETY REVIEWS (2013)

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Article Chemistry, Physical

Conjugated polyelectrolyte and zinc oxide stacked structure as an interlayer in highly efficient and stable organic photovoltaic cells

Yi-Ming Chang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Article Chemistry, Multidisciplinary

Inverted polymer solar cells with 8.4% efficiency by conjugated polyelectrolyte

Tingbin Yang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Article Optics

High-efficiency inverted dithienogermole-thienopyrrolodione-based polymer solar cells

Cephas E. Small et al.

NATURE PHOTONICS (2012)

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Article Multidisciplinary Sciences

A Universal Method to Produce Low-Work Function Electrodes for Organic Electronics

Yinhua Zhou et al.

SCIENCE (2012)

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Article Chemistry, Multidisciplinary

Inverted Polymer Solar Cells Integrated with a Low-Temperature-Annealed Sol-Gel-Derived ZnO Film as an Electron Transport Layer

Yanming Sun et al.

ADVANCED MATERIALS (2011)

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Article Chemistry, Multidisciplinary

Interface Engineering for Organic Electronics

Hong Ma et al.

ADVANCED FUNCTIONAL MATERIALS (2010)

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Article Chemistry, Physical

Hybrid zinc oxide conjugated polymer bulk heterojunction solar cells

WJE Beek et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2005)

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Article Chemistry, Physical

Novel electroluminescent conjugated polyelectrolytes based on polyfluorene

F Huang et al.

CHEMISTRY OF MATERIALS (2004)

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