Phosphate anion-induced silver-chalcogenide cluster-based metal organic frameworks as dual-functional catalysts for detoxifying chemical warfare agent simulants

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Silver Cluster-Porphyrin-Assembled Materials as Advanced Bioprotective Materials for Combating Superbacteria

Man Cao et al.

Summary: The newly established Ag-9-AgTPyP framework demonstrates superior superbugs-killing efficiency, outperforming the majority of bacteria inactivation photocatalysts, with unique advantages in oxygen production and transportation.

ADVANCED SCIENCE (2022)

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Article Multidisciplinary Sciences

Nuclearity enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D network formation driven by bipyridines

Zhi Wang et al.

Summary: This study reports the structural transformations of silver nanoclusters under different ligand templates and demonstrates that the transformations can be achieved through reactions with specific ligands. The findings provide a powerful method for synthesizing metal nanoclusters and infinite networks, and have the potential to evolve from trial-and-error to rational synthesis.

NATURE COMMUNICATIONS (2022)

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Review Chemistry, Multidisciplinary

Metal nanocluster-based devices: Challenges and opportunities

Lizhen Chen et al.

Summary: NCs possess unique physicochemical characteristics and have gained widespread attention in various fields; recent research shows high potential for metal NCs applications in multidisciplinary areas; through synthesis challenges and related application studies, NC-based devices have promising prospects for development.

AGGREGATE (2022)

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Review Chemistry, Inorganic & Nuclear

Recent advances in polyoxometalate-templated high-nuclear silver clusters

Rui Ge et al.

Summary: The search for feasible strategies to construct high-nuclear silver clusters using anions as templates, such as polyoxometalates (POMs), has attracted continuous interest. POMs have been widely employed to direct the formation of silver clusters and stabilize the final products, showcasing promising applications in various fields.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Nanoscience & Nanotechnology

Superoxide Ion and Singlet Oxygen Photogenerated by Metalloporphyrin-Based Metal-Organic Frameworks for Highly Efficient and Selective Photooxidation of a Sulfur Mustard Simulant

Zi-Hao Long et al.

Summary: A new type of metal-organic framework was studied as a photocatalyst for the degradation of chemical warfare agents, effectively oxidizing sulfur mustard simulant and proposing a new detoxification strategy.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Assembly of Chiral Cluster-Based Metal-Organic Frameworks and the Chirality Memory Effect during their Disassembly

Guocheng Deng et al.

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

Shell engineering to achieve modification and assembly of atomically-precise silver clusters

Yan Jin et al.

Summary: This review summarizes the progress in the preparation and structural determination of monolayer-protected silver clusters, focusing on the strategies and methods for precise modification and hierarchical assembly of silver clusters through shell engineering. The correlations between structure-property and structure-functionality of silver clusters are discussed, with particular emphasis on the structure-luminescence relationship and the potential of silver clusters as lighting materials. The challenges and perspectives of functional silver clusters are also highlighted, aiming to inspire the development of functionality-oriented materials based on nanosized building blocks in the fields of nanotechnology and material science.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Multidisciplinary

Atomically Precise Noble Metal Nanoclusters as Efficient Catalysts: A Bridge between Structure and Properties

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CHEMICAL REVIEWS (2020)

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Review Chemistry, Multidisciplinary

State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis

Qi Wang et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Recent Progress in Inorganic Anions Templated Silver Nanoclusters: Synthesis, Structures and Properties

Zhi Wang et al.

CHEMICAL RECORD (2020)

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A Sodalite-Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster

Chenglong Deng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Metal-Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives

Anastasiya Bavykina et al.

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Ambient Chemical Fixation of CO2Using a Robust Ag27Cluster-Based Two-Dimensional Metal-Organic Framework

Meihua Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups

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NATURE COMMUNICATIONS (2020)

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Ligand engineering to achieve enhanced ratiometric oxygen sensing in a silver cluster-based metal-organic framework

Xi-Yan Dong et al.

NATURE COMMUNICATIONS (2020)

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Review Chemistry, Multidisciplinary

Silver nanoclusters: synthesis, structures and photoluminescence

Yun-Peng Xie et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

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Review Chemistry, Multidisciplinary

Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications

Ulku Kokcam-Demir et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Materials Science, Multidisciplinary

Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

Dennis T. Lee et al.

MATTER (2020)

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Article Chemistry, Multidisciplinary

Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks

Mohammad J. Alhilaly et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Porphyrinic Silver Cluster Assembled Material for Simultaneous Capture and Photocatalysis of Mustard-Gas Simulant

Man Cao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Improving the Efficiency of Mustard Gas Simulant Detoxification by Tuning the Singlet Oxygen Quantum Yield in Metal-Organic Frameworks and Their Corresponding Thin Films

Cassandra T. Buru et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Multidisciplinary

Tandem Silver Cluster Isomerism and Mixed Linkers to Modulate the Photoluminescence of Cluster-Assembled Materials

Ren-Wu Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Review Chemistry, Multidisciplinary

Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

Lichen Liu et al.

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Silver Clusters as Robust Nodes and pi-Activation Sites for the Construction of Heterogeneous Catalysts for the Cycloaddition of Propargylamines

Zhiduo Chang et al.

ACS CATALYSIS (2018)

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Review Chemistry, Multidisciplinary

Surface Chemistry of Atomically Precise Coinage-Metal Nanoclusters: From Structural Control to Surface Reactivity and Catalysis

Juanzhu Yan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

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Article Chemistry, Multidisciplinary

Singlet Oxygen-Engaged Selective Photo-Oxidation over Pt Nanocrystals/Porphyrinic MOF: The Roles of Photothermal Effect and Pt Electronic State

Yu-Zhen Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Multidisciplinary

Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal-organic framework

Ren-Wu Huang et al.

NATURE CHEMISTRY (2017)

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Role of Anions Associated with the Formation and Properties of Silver Clusters

Quan-Ming Wang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

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Article Chemistry, Multidisciplinary

Selective Photooxidation of a Mustard-Gas Simulant Catalyzed by a Porphyrinic Metal-Organic Framework

Yangyang Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Metal Organic Framework Catalysis: Quo vadis?

Jorge Gascon et al.

ACS CATALYSIS (2014)

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Review Biochemical Research Methods

Fluorescence probes used for detection of reactive oxygen species

A Gomes et al.

JOURNAL OF BIOCHEMICAL AND BIOPHYSICAL METHODS (2005)

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Phosphate anion-induced silver-chalcogenide cluster-based metal organic frameworks as dual-functional catalysts for detoxifying chemical warfare agent simulants

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