Circular indirect carbonation of coal fly ash for carbon dioxide capture and utilization

Mineral carbonation of alkaline wastes is a promising route for carbon dioxide (CO2) capture and utilization. An exploration of the carbonation potential of relatively inert alkaline wastes is important to develop mineral carbonation. Large amounts of coal fly ash are generated from coal-fired power plants and must be treated. A fundamental study of the circular indirect carbonation of coal fly ash was proposed and fly-ash leaching, calcium carbonate (CaCO3) precipitation, and solution regeneration with bipolar membrane electrodialysis (BPED) stages were investigated. In the leaching stage, the nitric acid/calcium ratio affected the solution pH and impurity concentration. The leaching behavior of impurities was related mainly to colloidal precipitation. Approximately 97.3% calcium in solution reacted to form precipitated CaCO3, and a higher-purity CaCO3 precipitate was ob-tained when a lower nitric acid/calcium ratio was used in the leaching stage. The CO2 conversion was 92.9% and the CO2 uptake efficiency was-0.011 g-CO2/g-fly ash, which can be improved by optimizing the liquor puri-fication process. Fundamental liquor purification was performed. Solution regeneration by BPED was evaluated by investigating the effect of electric potential and current density on the regeneration yield, current efficiency, and power consumption. A comprehensive assessment, including cost and CO2 balance, was conducted, and future interesting research on circular indirect carbonation was suggested.

Automated summary

Mineral carbonation of alkaline wastes is a promising method for capturing and utilizing carbon dioxide (CO2). Exploring the carbonation potential of relatively inert alkaline wastes is crucial for developing mineral carbonation. This study conducted a fundamental investigation on the circular indirect carbonation of coal fly ash and examined the stages of fly-ash leaching, calcium carbonate precipitation, and solution regeneration. By optimizing the liquor purification process, the CO2 conversion rate and uptake efficiency can be improved.