期刊
CRYSTALS
卷 6, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/cryst6050060
关键词
closo-decaborate; closo-dodecaborate; 1-carba-closo-decaborate; carba-closo-decaborate; cobalt bis(dicarbollide); copper; silver; complexes; structure
资金
- Russian Science Foundation [14-13-01115]
- Russian Science Foundation [14-13-01115] Funding Source: Russian Science Foundation
Synthesis and structure of silver and copper salts and complexes with polyhedral boron hydride anions, including closo-decaborate [B10H10](2-), closo-dodecaborate [B12H12](2-), 1-carba-closo-decaborate [1-CB9H10](-), carba-closo-dodecaborate [CB11H12](-), and cobalt bis(dicarbollide)[3,3'-Co(1,2-C2B9H11)(2)](-) anions and their derivatives, are reviewed. The complexes demonstrate a wide variety of structural types, relating to both the metal coordination environment and coordination modes of boron hydride anions. The latter can range from strong coordination via the polyhedron triangular face including formation of 3c-2e MHB bonds in the case of the [B10H10](2-) dianion, the structure of which contains two four-coordinated boron atoms, to very weak M center dot center dot center dot H interactions with the hydride atoms in the case of bulky [3,3'-Co(1,2-C2B9H11)(2)](-) monoanion.
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