4.6 Article

Rheological behavior of thread-like fiber solutions formed from a rosin-based surfactant with two head groups

期刊

SOFT MATTER
卷 18, 期 35, 页码 6694-6702

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sm00964a

关键词

-

资金

  1. National Natural Science Foundation of China [31670575]

向作者/读者索取更多资源

In this study, a novel rosin-based quaternary ammonium surfactant was synthesized to form thread-like aggregates with rigidity. The solution showed remarkable viscoelasticity at very low surfactant concentrations and exhibited excellent shear resistance and weak sensitivity to temperature.
Wormlike micelles are conventional aggregates that exist in viscoelastic solutions. However, to achieve a solution with prominent viscoelasticity, rather high concentrations of surfactants are usually required due to the flexibility of aggregates in solution. If thread-like aggregates with rigidity can be formed by surfactants, the solutions are expected to show strong viscoelasticity at very low surfactant concentrations. Herein, A novel rosin-based quaternary ammonium surfactant with two head groups (abbreviated as R-11-3-DA) was synthesized. Cryogenic transmission electron microscopy (Cryo-TEM) images showed that flexible nanofibers with diameters of about 7-8 nm and lengths of over 1 mu m were formed in the 1 : 1.5 R-11-3-DA : SL solutions. The rigidity of the aggregates seems to be inherited from the rigidity of the surfactant molecules. The novel aggregates endow the solutions with remarkable viscoelasticity at very low concentrations, with a critical overlap concentration of 0.01 wt% and a critical gelling concentration of 0.58 wt%. The rheological behavior of the solutions also shows excellent shear resistance and weak sensitivity to temperature below the critical gelation temperature (T-gel). This work reveals the advantages of viscoelastic solutions containing flexible nanofibers. The design principles of new molecular structures and system compositions can be applied to the preparation of smart soft materials based on the self-assembly of molecules.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据