4.7 Article

Distinct modes of Si-H binding to Rh in complexes of a phosphine-diarylamido-silane (SiNP) pincer ligand

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Summary: Unsaturated 16-electron iridium and rhodium complexes with a silyl-bipyridine-based SiNN-pincer ligand (Bpy(SiNN)) were synthesized and characterized. The iridium-Bpy(SiNN) complex successfully catalyzed the C(sp(2))-H borylation of arenes under mild conditions (around 40 degrees C), yielding arylboronate esters with high yields (>= 93%).

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