期刊
DALTON TRANSACTIONS
卷 51, 期 37, 页码 14150-14155出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt02175g
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资金
- US National Science Foundation [CHE-1565923, CHE-2102324, CHE-1359175]
- State Key Laboratory of Urban Water Resource and Environment (Harbin Institute of Technology) [2022TS36]
- AGEP-GRS supplements
Syntheses of Rh complexes of the phosphine-amido-silane SiNP ligand are described. Different complexes can be obtained through various reactions and treatment.
Syntheses of Rh complexes of the phosphine-amido-silane SiNP ligand are reported. The reaction of the parent (SiNP)H ligand (4) with 0.5 equiv. [(COE)RhCl](2) (COE = cis-cyclooctene) in the presence of NaN (SiME3)(2) resulted in the formation of (SiNP)Rh(COE) (5). Compound 5 was converted to a series of (SiNP) Rh(P(OR)(3)) complexes 6-10 (R = Ph,Pr- i, Bu-n, Et, or Me) by treatment with the corresponding phosphite. NMR and XRD structural data, as well as the DFT computational analysis indicate that compounds 5-10 are divided into two structural Types (A and B), differing in the nature of the interaction of the Si-H bond of the SiNP ligand with Rh.
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