A simple synthesis of surfactant-free polycrystalline CuO nanoparticles supported on carbon nanofibers for regioselective hydroboration of alkynes

Copper oxide nanoparticles (CuO NPs) with a clean surface supported on carbon nanofibers (CNFs) in one-pot were prepared by simple solid-state grinding and aging followed by thermal treatment, yielding CuO nanoparticles with high (23.8 wt%) and uniform CuO loading in the absence of surfactants and solvent. The CuO NPs on CNFs (CuO/CNF) showed excellent catalytic activity in transforming a wide variety of alkynes into alkenyl boronates using B(2)Pin(2) as a boron source in the absence of ligand and additives with high regioselectivity under mild conditions. Moreover, the present CuO/CNF catalyst was recyclable and possesses excellent chemoselectivity. The developed green synthetic approach is expected to offer exciting opportunities for designing monometallic or bimetallic nanoparticle catalysts on different supports applied in heterogeneous catalysis.

Automated summary

CuO nanoparticles with a clean surface supported on carbon nanofibers were prepared by solid-state grinding and aging followed by thermal treatment. These CuO/CNF catalysts showed excellent catalytic activity in transforming alkynes into alkenyl boronates with high regioselectivity under mild conditions, and they were also recyclable.