期刊
GREEN CHEMISTRY
卷 24, 期 18, 页码 6849-6853出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2gc02438a
关键词
-
资金
- Natural Science Foundation of China [32171724]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX22_1087]
- Advanced Analysis and Testing Center of Nanjing Forestry University
In this study, an environmentally friendly synthesis of arylthioesters using water as the medium and photoredox catalysis was reported. The coupling of acyl oxime acetates with thiophenols was achieved through the synergistic action of an organophotocatalyst and a phase-transfer catalyst under blue light conditions.
Photoredox catalysis in water has been receiving increasing attention due to its merits of being environment friendly, inexpensive, and safe. However, efficient approaches to arylthioesters via photoredox catalysis in water remain unknown. We herein report an environmentally responsible synthesis of arylthioesters through the coupling of acyl oxime acetates with thiophenols. This protocol was achieved in water with Eosin Y as the organophotocatalyst, MPEG-550 as the phase-transfer catalyst, and blue light. Preliminary mechanistic studies suggested a radical-radical coupling of an acyl radical with a thiyl radical.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据