期刊
MATERIALS CHEMISTRY FRONTIERS
卷 6, 期 19, 页码 2913-2920出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qm00329e
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资金
- DST-FIST [SR/FST/ETI-421/2016]
In this work, beta-NaAlO2 nanoflakes were synthesized and demonstrated as a high performance, long-life anode material for sodium-ion batteries. The outstanding performance and excellent cyclability of the beta-NaAlO2 anode make it a highly stable and cost-effective material for high-energy sodium-ion batteries.
New anode materials for sodium-ion batteries are being extensively studied to achieve high stability and long-term cyclability. In this work, we demonstrate the solid-state synthesis of beta-NaAlO2 nanoflakes as a high performance, long-life anode material for sodium-ion batteries (SIBs). The beta-NaAlO2 nanoflakes exhibit a theoretical capacity of similar to 326.69 mA h g(-1). The as-assembled SIB with beta-NaAlO2 as the anode material exhibits an initial discharge capacity of similar to 318 mA h g(-1) at 0.1C-rate (1st cycle). The SIB displays a discharge capacity of similar to 183 mA h g(-1) after 1000 cycles with a coulombic efficiency of 92%. This outstanding performance with the long-term cyclability of the beta-NaAlO2 anode can be ascribed to the Al3+ in the structure that reduces the Jahn-Teller distortion effect during the process of sodiation and desodiation cycles. The good cyclability of the beta-NaAlO2 anode proves it to be a highly stable and cost-effective anode material for high-energy SIBs.
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