4.6 Article

Zinc stannate microcubes with an integrated microheater for low-temperature NO2 detection

期刊

NEW JOURNAL OF CHEMISTRY
卷 46, 期 37, 页码 17967-17976

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj02709g

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资金

  1. Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division, of the US Department of Energy within the van der Waals Heterostructures Program [DE-AC02-05-CH11231, KCWF16]
  2. Berkeley Sensor and Actuator Center (BSAC), an Industry/University Research Cooperation Center
  3. Sao Paulo Research Foundation (FAPESP) [2014/23546-1, 2016/23474-6, 2018/22214-6, 2013/07296-2]
  4. CNPq (Brazil)

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This paper presents a facile technique to fabricate an oxide nanostructured film on a low-power microheater sensor platform for highly sensitive and selective detection of NO2 gas at low temperature. Microcube-shaped ZnSnO3 nanostructures prepared by co-precipitation method exhibit excellent gas sensing performance, attributed to their porous surface providing large surface area and suitable absorption-desorption processes.
This paper reports a facile technique to construct an oxide nanostructured film on a low-power microheater sensor platform to detect NO2 gas with high sensitivity and selectivity at a low temperature. Microcube-shaped zinc stannate (ZnSnO3) nanostructures prepared through a co-precipitation method were used to detect NO2 down to 85 ppb at 110 degrees C with a fast response and recovery time. Specifically, a 192% response in the resistance change was measured for 5 ppm NO2 gas, with a response time of 3.36 mins, excellent reproducibility, long-term stability, and high selectivity. The good gas-sensing performance of the ZnSnO3 microcubes is due to their porous surface, which provides a large surface area and suitable absorption-desorption processes. The versatility of the ZnSnO3 nanostructures may be further exploited with various sensing units on a single chip towards the development of arrays, as in electronic noses.

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