Impact of Electrode Defects on Battery Cell Performance: A Mini Review

The continuing rise of electric mobility is driving demand for lithium-ion batteries to unprecedented levels. To ensure efficient production of high quality, yet affordable battery cells, while making the best use of available raw materials and processes, reasonable quality assurance criteria are needed. A step of particular importance, affecting all downstream processes, lies in electrode manufacturing including mixing, coating, drying, and calendering. Several classes of defects which originate in these processes are well-known and detectable using various methods. The crucial point, however, lies in the quantification of their electrochemical significance, i.e., in an evaluation, which defect types, sizes and concentrations can be tolerated without impacting cell performance. Herein, we review the still scarce literature on that topic. It is found that, although the impact of some defects is quite well understood, others almost completely lack an evaluation of their criticality. We finally make suggestions for further studies paving the way to deduce knowledge-based quality assurance criteria for the large variety of coating defects occurring in lithium-ion battery electrodes.

Automated summary

The rise of electric mobility has led to unprecedented demand for lithium-ion batteries. To ensure efficient production of high-quality and affordable battery cells, reasonable quality assurance criteria are needed, particularly in electrode manufacturing processes. This review highlights the importance of quantifying the electrochemical significance of defects in lithium-ion battery electrodes. It also emphasizes the need for further studies to establish knowledge-based quality assurance criteria for coating defects.