4.6 Review

Thermal, chemical, electrochemical, radiolytic and biological stability of ionic liquids and deep eutectic solvents

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Article Engineering, Chemical

Mild and efficient recovery of lithium-ion battery cathode material by deep eutectic solvents with natural and cheap components

Yu Chen et al.

Summary: The dissolution of lithium cobalt oxide (LCO) is crucial for the recovery of valuable metals from spent lithium-ion batteries. Deep eutectic solvents (DESs) with polyethylene glycol (PEG) as hydrogen bond acceptor and ascorbic acid (AA) as hydrogen bond donor are found to efficiently dissolve LCO, offering a green and sustainable solution for LCO dissolution.

GREEN CHEMICAL ENGINEERING (2023)

Article Engineering, Chemical

Application-Related Consideration of the Thermal Stability of [mTBDH][OAc] Compared to Amidine-Based Ionic Liquids in the Presence of Various Amounts of Water

Inge Schlapp-Hackl et al.

Summary: The hydrolysis kinetics of 7-methyl-1,5,7-triazabicyclo [4.4.0] dec-5- enium acetate [mTBDH] [OAc] were comprehensively studied to investigate its stability for dry-jet wet spinning applications and recovery methods. The decomposition behavior was analyzed and characterized by NMR, CE, and TGA. Kinetic models were formulated for stability prediction and compared with similar compounds DBNH and DBUH.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2022)

Article Chemistry, Multidisciplinary

Deep eutectic solvents as a green toolbox for synthesis

Dongkun Yu et al.

Summary: Deep eutectic solvents (DESs), as a class of green and easily modified solvents composed of monomers from biological sources, have been widely used in both laboratory and industrial scales. This review focuses on four strategies for materials synthesis using DESs: solvothermal methods, electrodeposition, calcination, and polymerization.

CELL REPORTS PHYSICAL SCIENCE (2022)

Review Chemistry, Physical

CO2 capture and conversion to value-added products promoted by MXene-based materials

Yu Chen et al.

Summary: This review discusses the capture, sensing, and conversion of CO2 using MXene and MXene-based materials, and summarizes the underlying mechanisms. The findings provide new insights for efficient CO2 utilization and widespread applications.

GREEN ENERGY & ENVIRONMENT (2022)

Review Engineering, Chemical

Recovery of natural active molecules using aqueous two-phase systems comprising of ionic liquids/deep eutectic solvents

Yicong Wang et al.

Summary: This paper discusses the research progress in extracting bioactive compounds from plant materials using environmentally friendly green solvents, and introduces the application of ionic liquids and deep eutectic solvents in the extraction process.

GREEN CHEMICAL ENGINEERING (2022)

Article Chemistry, Physical

Design and prediction for highly efficient SO2 capture from flue gas by imidazolium ionic liquids

Lili Jiang et al.

Summary: An efficient method for predicting the capture of SO2 from flue gas using imidazolium ionic liquids was reported. Through quantitative calculations and design, the absorption performance of various imidazolium ionic liquids for SO2 was predicted and validated through experiments.

GREEN ENERGY & ENVIRONMENT (2022)

Article Environmental Sciences

Ecotoxicity and biodegradability of pure and aqueous mixtures of deep eutectic solvents: glyceline, ethaline, and reline

David Lapena et al.

Summary: The study investigated the ecotoxicity of three pure deep eutectic solvents and their mixtures with water, finding low toxicities in different biomodels and considering most solvents readily biodegradable. A complete analysis comparing ecotoxicity and biodegradability under other conditions was provided.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

Article Chemistry, Physical

Total vapor pressure of hydrophobic deep eutectic solvents: Experiments and modelling

Kun Xin et al.

Summary: Headspace gas chromatography mass spectrometry (HS-GC-MS) was used to study the volatility of six selected hydrophobic deep eutectic solvents (DESs), deepening the understanding of the thermodynamic nature of DESs by measuring and predicting activity coefficients between constituents. It was found that interactions between DES constituents weaken with increasing temperature.

JOURNAL OF MOLECULAR LIQUIDS (2021)

Article Thermodynamics

Impacts of TGA furnace parameters for prediction of long-term thermal stability of ionic liquids

Andre Meissner et al.

Summary: By conducting kinetic evaluation through thermogravimetric analysis, the concept of maximum operation temperature has been successfully established for predicting the thermal stability of ionic liquids. The influence of furnace control parameters on thermal decomposition kinetics of 1-methyl-3-propylimidazolium iodide has been studied, showing variations in activation energy based on the degree of decomposition. The activation energy, pre-exponential factor, and the activation energy are highly dependent on the parameters of the TGA furnace controller.

THERMOCHIMICA ACTA (2021)

Review Engineering, Chemical

Thermal Stability of Ionic Liquids: Current Status and Prospects for Future Development

Chenqian Xu et al.

Summary: Ionic liquids are considered the safest solvents in high-temperature applications due to their non-flammable properties, with thermogravimetric analysis being extensively used for studying their thermal stability. Isoconversional methods are found to be superior to Arrhenius methods in calculating activation energy, and the use of compensation effect and master plots is suggested for pre-exponential factor calculation. The structure of cations has some influence on thermal stability, but anions play a larger role. Developing dicationic ILs can lead to enhanced thermal stability.

PROCESSES (2021)

Article Chemistry, Physical

Long-term thermal stability of fatty acid anion-based ionic liquids

B. Ramajo et al.

Summary: The thermal degradation of 8 novel fatty acid anion-based ionic liquids (FAILs) was studied, revealing that their thermal stability is influenced by both the cation and anion, with most having an onset decomposition temperature below 200 degrees C. Compared to commercially available ILs tested previously in lubrication studies, especially those containing the [NTf2](-) anion, the FAILs exhibited lower thermal stability under a nitrogen atmosphere. Among them, [N-8,N-8,N-8,N-1][C-6:0] and [N-8,N-8,N-8,N-1][C-8:0] showed the highest long-term thermal stability.

JOURNAL OF MOLECULAR LIQUIDS (2021)

Article Chemistry, Physical

Thermal Stability and Decomposition Kinetics of 1-Alkyl-2,3-Dimethylimidazolium Nitrate Ionic Liquids: TGA and DFT Study

Jianwen Meng et al.

Summary: This study investigated the thermal stability and decomposition kinetics of 1-alkyl-2,3-dimethylimidazole nitrate ionic liquids with different alkyl chains, and found that the thermal stability decreases and thermal hazard increases with longer alkyl chains on the cation. These results can provide guidance for the safety design and use of imidazolium nitrate ionic liquids in engineering.

MATERIALS (2021)

Article Chemistry, Multidisciplinary

Significant Improvement in Dissolving Lithium-Ion Battery Cathodes Using Novel Deep Eutectic Solvents at Low Temperature

Yu Chen et al.

Summary: A novel deep eutectic solvent based on poly(ethylene glycol) 200 and p-toluenesulfonic acid monohydrate has been designed for the efficient dissolution of lithium cobalt oxide (LCO). The dissolution efficiency is nearly 100% at 100 degrees C within 24 hours, surpassing previous reports. The interaction between the deep eutectic solvent and LCO is found to be a physical process, providing a new strategy for the mild and efficient dissolution of LCO using inexpensive and environmentally friendly solvents.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Engineering, Chemical

Prediction of CO2 solubility in deep eutectic solvents using random forest model based on COSMO-RS-derived descriptors

Jingwen Wang et al.

Summary: This study developed a molecular-based mathematical model for predicting CO2 solubility in deep eutectic solvents (DESs). By establishing a comprehensive database, calculating descriptors, and using regression and machine learning methods for analysis, a reliable prediction model was suggested for CO2 solubility in DESs.

GREEN CHEMICAL ENGINEERING (2021)

Review Chemistry, Physical

Boron based hypergolic ionic liquids: A review

Zhenyu Zhang et al.

Summary: Boron-based HILs with low viscosity have emerged as new potential fuels for bipropellant systems, and their derivatives can enhance hypergolicity as additives in HILs.

GREEN ENERGY & ENVIRONMENT (2021)

Article Chemistry, Physical

Machine learning and high-throughput computational screening of hydrophobic metal-organic frameworks for capture of formaldehyde from air

Xueying Yuan et al.

Summary: By analyzing a large number of metal-organic frameworks, the study identified the top-performing MOFs for capturing formaldehyde from the air and proposed a new performance metric, TSC, to balance selectivity and capacity. The research also determined the characteristics of different materials for capturing formaldehyde from the air, providing quantitative guidance for the design of excellent adsorbents.

GREEN ENERGY & ENVIRONMENT (2021)

Article Engineering, Environmental

Photodegradation of an ammonium ionic liquid: spiking in urban wastewater and comparison with aromatic ionic liquids

Sandesh S. Raut et al.

Summary: This study investigates the photocatalytic degradation of a new quaternary ammonium ionic liquid pollutant by Ag-doped SnO2 nanoparticles. By analyzing the parameters and pathways of photocatalytic degradation, it was found that the 5% Ag-SnO2 catalyst can efficiently degrade all pollutants within 300 minutes.

ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY (2021)

Review Chemistry, Physical

Ionic liquids/deep eutectic solvents for CO2 capture: Reviewing and evaluating

Yanrong Liu et al.

Summary: This study comprehensively collected and summarized the solubilities of CO2 in physical- and chemical-based ILs/DESs, as well as the COSMO-RS models predicting these properties. Chemical-based ILs/DESs were found to be more effective for CO2 capture, especially those with functionalized cations and anions, and superbase DESs.

GREEN ENERGY & ENVIRONMENT (2021)

Article Chemistry, Physical

Evaluation of COSMO-RS for solid-liquid equilibria prediction of binary eutectic solvent systems

Zhen Song et al.

Summary: This study systematically evaluates the SLE prediction of binary eutectic solvent systems using the COSMO-RS model, comparing experimental and predicted eutectic points. The impact of salt component conformer, COSMO-RS parameterization, and the applicability for different types of components are identified, and the performance of COSMO-RS SLE prediction is interpreted from non-ideality and fusion enthalpy perspectives.

GREEN ENERGY & ENVIRONMENT (2021)

Article Chemistry, Physical

Machine learning-based ionic liquids design and process simulation for CO2 separation from flue gas

Kai Wang et al.

Summary: A support vector machine (SVM) model was established to improve the prediction accuracy and range of ionic liquids (ILs) melting points. Through this model and other design processes, the most suitable IL for CO2 separation was identified.

GREEN ENERGY & ENVIRONMENT (2021)

Article Chemistry, Physical

Chlorine drying with hygroscopic ionic liquids

Gangqiang Yu et al.

Summary: The study proposes and investigates the chlorine drying technology using ionic liquids as absorbents from molecular to industrial level, revealing a promising absorbent [EMIM][CH3SO3] with potential for industrialization due to its lower IL amount and energy consumption.

GREEN ENERGY & ENVIRONMENT (2021)

Review Chemistry, Multidisciplinary

Eutectics: formation, properties, and applications

Dongkun Yu et al.

Summary: Various eutectic systems, including eutectic metals, eutectic salts, and deep eutectic solvents, have been proposed and studied in the past few decades. They have diverse applications in chemistry-related fields, with overlapping but distinct properties stemming from their different compositions. The introduction of new eutectic systems has driven the development of interdisciplinary research involving chemistry, materials, engineering, and energy.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Physical

Ionic liquid-derived core-shell gold@palladium nanoparticles with tiny sizes for highly efficient electrooxidation of ethanol

Hong Zhang et al.

Summary: By synthesizing core-shell gold (Au)@Palladium (Pd) nanoparticles in an ionic liquid, the study combines the advantages of ionic liquids in preparing fine metal nanoparticles and core-shell structures, resulting in nanomaterials smaller than 3 nm with high activity in ethanol electrooxidation, exceeding commercial Pd/C catalysts.

GREEN ENERGY & ENVIRONMENT (2021)

Article Chemistry, Physical

High volatility of superbase-derived eutectic solvents used for CO2 capture

Yu Chen et al.

Summary: The study finds that superbase-derived ESs are highly volatile, even at room temperature. The typical EG: DBU (4:1) solvent exhibits a three-stage volatilizing mechanism. ESs and their mixture with CO2 are highly volatile.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2021)

Article Engineering, Chemical

Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide

Jinghang Li et al.

CHINESE JOURNAL OF CHEMICAL ENGINEERING (2020)

Article Engineering, Chemical

Flammability hazard analysis of imidazolium-based ionic liquid binary mixtures under high temperatures

Yongheng Li et al.

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES (2020)

Article Chemistry, Physical

Insights into microwave heating response and thermal decomposition behavior of deep eutectic solvents

Jose Gonzalez-Rivera et al.

JOURNAL OF MOLECULAR LIQUIDS (2020)

Article Chemistry, Physical

Decomposition of deep eutectic solvents based on choline chloride and phenol in aqueous phase

Andrey Shishov et al.

JOURNAL OF MOLECULAR LIQUIDS (2020)

Review Chemistry, Physical

The role of water in deep eutectic solvent-base extraction

Maria Vilkova et al.

JOURNAL OF MOLECULAR LIQUIDS (2020)

Article Chemistry, Multidisciplinary

Capture of Toxic Gases by Deep Eutectic Solvents

Yu Chen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Visible Light-Driven Photoreduction of CO2 to CH4 over TiO2 Using a Multiple-Site Ionic Liquid as an Absorbent and Photosensitizer

Yu Chen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Physical

High voltage supercapacitor based on non flammable high -concentration-ionic liquid electrolyte

Junhong Guo et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

Article Chemistry, Physical

Surface tension and surface thermodynamic properties of PEG-based deep eutectic solvents

Yu Chen et al.

JOURNAL OF MOLECULAR LIQUIDS (2020)

Review Chemistry, Analytical

Deep eutectic solvents are not only effective extractants

Andrey Shishov et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Electrochemical oxidation as alternative for dissolution of metal oxides in deep eutectic solvents

Ioanna M. Pateli et al.

GREEN CHEMISTRY (2020)

Article Chemistry, Physical

Insights into the Nature of Eutectic and Deep Eutectic Mixtures

Monia A. R. Martins et al.

JOURNAL OF SOLUTION CHEMISTRY (2019)

Article Engineering, Chemical

Volatility of Deep Eutectic Solvent Choline Chloride:N-Methylacetamide at Ambient Temperature and Pressure

Yu Chen et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Electrochemistry

Influence of additives on the electrodeposition of zinc from a deep eutectic solvent

Hasan F. Alesary et al.

ELECTROCHIMICA ACTA (2019)

Article Engineering, Environmental

Increased flammability hazard when ionic liquid [C6mim] [Cl] is exposed to high temperatures

Horng-Jang Liaw et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

Article Chemistry, Multidisciplinary

Degradation of Deep-Eutectic Solvents Based on Choline Chloride and Carboxylic Acids

Nerea Rodriguez Rodriguez et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Energy & Fuels

Deep eutectic solvents for cathode recycling of Li-ion batteries

Mai K. Tran et al.

NATURE ENERGY (2019)

Article Engineering, Chemical

Fire and explosion hazards of ionic liquid 1-methyl-1-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide

Chan-Cheng Chen et al.

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES (2019)

Article Chemistry, Analytical

In situ decomposition of deep eutectic solvent as a novel approach in liquid-liquid microextraction

Andrey Shishov et al.

ANALYTICA CHIMICA ACTA (2019)

Review Chemistry, Physical

Application of deep eutectic solvents in biomass pretreatment and conversion

Yu Chen et al.

GREEN ENERGY & ENVIRONMENT (2019)

Review Chemistry, Multidisciplinary

Conversion of CO2 to value-added products mediated by ionic liquids

Yu Chen et al.

GREEN CHEMISTRY (2019)

Article Chemistry, Physical

Bronsted acidity in deep eutectic solvents and ionic liquids

Andrew P. Abbott et al.

FARADAY DISCUSSIONS (2018)

Article Chemistry, Physical

Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis

Noemi Delgado-Mellado et al.

JOURNAL OF MOLECULAR LIQUIDS (2018)

Article Chemistry, Physical

First-Principles Molecular Dynamics Study of a Deep Eutectic Solvent: Choline Chloride/Urea and Its Mixture with Water

Evgenii O. Fetisov et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2018)

Article Chemistry, Physical

A closer look into deep eutectic solvents: exploring intermolecular interactions using solvatochromic probes

C. Florindo et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2018)

Article Chemistry, Physical

Thermal, electrochemical and radiolytic stabilities of ionic liquids

Zhimin Xue et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2018)

Article Chemistry, Physical

Janus-faced role of water in defining nanostructure of choline chloride/glycerol deep eutectic solvent

Lindong Weng et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2018)

Article Chemistry, Physical

Bronsted acidity in deep eutectic solvents and ionic liquids

Andrew P. Abbott et al.

FARADAY DISCUSSIONS (2018)

Article Engineering, Chemical

Plasmon-Enhanced Photodegradation of Ionic Liquids with Ag Nanocubes/ZnO Microsphere Composites

Weiwei Lu et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2018)

Article Chemistry, Physical

Investigation on the Thermal Stability of Deep Eutectic Solvents

Chen Wenjun et al.

ACTA PHYSICO-CHIMICA SINICA (2018)

Article Materials Science, Paper & Wood

Long-term Isothermal Stability of Deep Eutectic Solvents

Michal Jablonsky et al.

BIORESOURCES (2018)

Article Engineering, Chemical

Flammability characteristics of ionic liquid 1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Chan-Cheng Chen et al.

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES (2017)

Article Chemistry, Organic

Organocatalytic Imidazolium Ionic Liquids H/D Exchange Catalysts

Marcileia Zanatta et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

The Effect of Water upon Deep Eutectic Solvent Nanostructure: An Unusual Transition from Ionic Mixture to Aqueous Solution

Oliver S. Hammond et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Are Ionic Liquids Chemically Stable?

Binshen Wang et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Physical

Thermogravimetric measurement of deep eutectic solvents vapor pressure

Kaveh Shahbaz et al.

JOURNAL OF MOLECULAR LIQUIDS (2016)

Article Chemistry, Multidisciplinary

The electrochemical stability of ionic liquids and deep eutectic solvents

Qingbo Li et al.

SCIENCE CHINA-CHEMISTRY (2016)

Article Biotechnology & Applied Microbiology

Biodegradation of imidazolium ionic liquids by activated sludge microorganisms

Ewa Liwarska-Bizukojc et al.

BIODEGRADATION (2015)

Article Biotechnology & Applied Microbiology

Comparative study on the biodegradability of morpholinium herbicidal ionic liquids

Lukasz Lawniczak et al.

BIODEGRADATION (2015)

Article Engineering, Chemical

Evaporation and Decomposition Behavior of Pure and Supported Ionic Liquids under Thermal Stress

Florian Heym et al.

CHEMIE INGENIEUR TECHNIK (2015)

Article Environmental Sciences

Assessing the toxicity and biodegradability of deep eutectic solvents

Qing Wen et al.

CHEMOSPHERE (2015)

Article Environmental Sciences

Evaluation of toxicity and biodegradability of choline chloride based deep eutectic solvents

Kristina Radosevic et al.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2015)

Article Chemistry, Physical

Electrochemical fabrication of nanoporous copper films in choline chloride-urea deep eutectic solvent

Q. B. Zhang et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

Article Chemistry, Multidisciplinary

The chemical stability of phosphonium-based ionic liquids under gamma irradiation

Ryan P. Morco et al.

RSC ADVANCES (2015)

Article Chemistry, Multidisciplinary

Processing of Leather Using Deep Eutectic Solvents

Andrew P. Abbott et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2015)

Article Chemistry, Multidisciplinary

Evaluation of toxicity and biodegradability for cholinium-based deep eutectic solvents

Ibrahim Juneidi et al.

RSC ADVANCES (2015)

Article Chemistry, Multidisciplinary

Borohydride Ionic Liquids and Borane/Ionic-Liquid Solutions as Hypergolic Fuels with Superior Low Ignition-Delay Times

Songqing Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Review Chemistry, Multidisciplinary

Deep Eutectic Solvents (DESs) and Their Applications

Emma L. Smith et al.

CHEMICAL REVIEWS (2014)

Article Chemistry, Physical

Improving the Alkaline Stability of Imidazolium Cations by Substitution

Huilong Dong et al.

CHEMPHYSCHEM (2014)

Article Chemistry, Physical

Vaporisation and thermal decomposition of dialkylimidazolium halide ion ionic liquids

Kevin R. J. Lovelock et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Article Chemistry, Physical

Targeting adequate thermal stability and fire safety in selecting ionic liquid-based electrolytes for energy storage

L. Chancelier et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Article Chemistry, Inorganic & Nuclear

A NOVEL METHOD FOR SYNTHESIS OF 1, 3-DIALKYLIMIDAZOLE-2-SELENONES IN WATER

Fengshou Tian et al.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS (2014)

Review Chemistry, Multidisciplinary

Ionic liquid thermal stabilities: decomposition mechanisms and analysis tools

Cedric Maton et al.

CHEMICAL SOCIETY REVIEWS (2013)

Article Chemistry, Physical

Alkaline Stable C2-Substituted Imidazolium-Based Anion-Exchange Membranes

Bencai Lin et al.

CHEMISTRY OF MATERIALS (2013)

Article Chemistry, Multidisciplinary

How safe are protic ionic liquids? Explosion of pyrrolidinium nitrate

Sil Wellens et al.

GREEN CHEMISTRY (2013)

Article Biotechnology & Applied Microbiology

Removal of imidazolium ionic liquids by microbial associations: Study of the biodegradability and kinetics

Ewa Liwarska-Bizukojc et al.

JOURNAL OF BIOSCIENCE AND BIOENGINEERING (2013)

Article Engineering, Environmental

(Eco)toxicity and biodegradability of selected protic and aprotic ionic liquids

Brezana Peric et al.

JOURNAL OF HAZARDOUS MATERIALS (2013)

Article Chemistry, Physical

Hydrogen Production in Aromatic and Aliphatic Ionic Liquids

Surajdevprakash B. Dhiman et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2013)

Article Multidisciplinary Sciences

Evaluation of Toxicity and Biodegradability of Cholinium Amino Acids Ionic Liquids

Xue-Dan Hou et al.

PLOS ONE (2013)

Article Chemistry, Multidisciplinary

Relationship between flash point of ionic liquids and their thermal decomposition

Horng-Jang Liaw et al.

GREEN CHEMISTRY (2012)

Article Engineering, Chemical

Quantitative Research on the Vaporization and Decomposition of [EMIM][Tf2N] by Thermogravimetric Analysis-Mass Spectrometry

Yu Chen et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2012)

Article Chemistry, Physical

The electrodeposition of silver composites using deep eutectic solvents

Andrew P. Abbott et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

Article Chemistry, Multidisciplinary

Efficient biodegradation of common ionic liquids by Sphingomonas paucimobilis bacterium

Concepcion Abrusci et al.

GREEN CHEMISTRY (2011)

Article Chemistry, Physical

Radiation stability of some room temperature ionic liquids

Ch. Jagadeeswara Rao et al.

RADIATION PHYSICS AND CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Microbial biodegradation and metabolite toxicity of three pyridinium-based cation ionic liquids

Kathryn M. Docherty et al.

GREEN CHEMISTRY (2010)

Article Chemistry, Multidisciplinary

Further studies on the biodegradation of ionic liquids

Leigh Ford et al.

GREEN CHEMISTRY (2010)

Article Chemistry, Multidisciplinary

Anaerobic biodegradability of ionic liquid cations under denitrifying conditions

Jennifer Neumann et al.

GREEN CHEMISTRY (2010)

Article Chemistry, Multidisciplinary

Novel biocompatible cholinium-based ionic liquids-toxicity and biodegradability

Marija Petkovic et al.

GREEN CHEMISTRY (2010)

Review Thermodynamics

Volatility of Aprotic Ionic Liquids - A Review

Jose M. S. S. Esperanca et al.

JOURNAL OF CHEMICAL AND ENGINEERING DATA (2010)

Article Chemistry, Physical

Hydrolysis of Tetrafluoroborate and Hexafluorophosphate Counter Ions in Imidazolium-Based Ionic Liquids

Mara G. Freire et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2010)

Article Chemistry, Multidisciplinary

EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals

John C. Walton et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Physical

Vapour pressure of ionic liquids

Markus Bier et al.

MOLECULAR PHYSICS (2010)

Article Chemistry, Inorganic & Nuclear

Anion effect on radiochemical stability of room-temperature ionic liquids under gamma irradiation

G. Le Rouzo et al.

DALTON TRANSACTIONS (2009)

Article Chemistry, Multidisciplinary

Phosphonium ionic liquids: design, synthesis and evaluation of biodegradability

Farzad Atefi et al.

GREEN CHEMISTRY (2009)

Review Biochemistry & Molecular Biology

On the Chemical Stabilities of Ionic Liquids

Subbiah Sowmiah et al.

MOLECULES (2009)

Article Chemistry, Physical

Electrodeposition of copper composites from deep eutectic solvents based on choline chloride

Andrew P. Abbott et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2009)

Article Chemistry, Physical

Hydrogen gas yields in irradiated room-temperature ionic liquids

Peter Tarabek et al.

RADIATION PHYSICS AND CHEMISTRY (2009)

Article Environmental Sciences

Biodegradation of oxygenated and non-oxygenated imidazolium-based ionic liquids in soil

Alberto Modelli et al.

CHEMOSPHERE (2008)

Article Chemistry, Inorganic & Nuclear

Stability of [MeBu3N][Tf2N] under gamma irradiation

Emilie Bosse et al.

DALTON TRANSACTIONS (2008)

Article Engineering, Chemical

Flammability and thermal analysis characterization of imidazolium-based ionic liquids

Douglas M. Fox et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2008)

Article Chemistry, Multidisciplinary

Pyridine ring opening at room temperature at a rhenium tricarbonyl bipyridine complex

Miguel A. Huertos et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Chemistry, Physical

γ-radiation effect on ionic liquid [bmim][BF4]

Mingying Qi et al.

RADIATION PHYSICS AND CHEMISTRY (2008)

Article Chemistry, Organic

Side reaction of cellulose with common 1-alkyl-3-methylimidazolium-based ionic liquids

Gerald Ebner et al.

TETRAHEDRON LETTERS (2008)

Article Chemistry, Organic

The chemistry of the C2 position of imidazolium room temperature ionic liquids

Elliot Ennis et al.

CURRENT ORGANIC SYNTHESIS (2007)

Article Biotechnology & Applied Microbiology

Biodegradability of imidazolium and pyridinium ionic liquids by an activated sludge microbial community

Kathryn M. Docherty et al.

BIODEGRADATION (2007)

Article Chemistry, Physical

Vapourisation of ionic liquids

James P. Armstrong et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2007)

Review Chemistry, Organic

Effects of ionic liquids on Pd-catalysed carbon-carbon bond formation

Vincenzo Calo et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2006)

Article Chemistry, Multidisciplinary

Room temperature ring-opening metathesis of pyridines by a transient TiC linkage

Brad C. Bailey et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

Article Chemistry, Multidisciplinary

Combustible ionic liquids by design: is laboratory safety another ionic liquid myth?

Marcin Smiglak et al.

CHEMICAL COMMUNICATIONS (2006)

Review Chemistry, Multidisciplinary

Energetic nitrogen-rich salts and ionic liquids

Rajendra P. Singh et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Article Chemistry, Multidisciplinary

Synthesis of nitrogen heterocycles by the ring opening of pyridinium salts

Aaron M. Kearney et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Article Chemistry, Multidisciplinary

Oxygen-balanced energetic ionic liquid

C. Bigler Jones et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Article Chemistry, Organic

The 2-position of imidazolium ionic liquids: Substitution and exchange

ST Handy et al.

JOURNAL OF ORGANIC CHEMISTRY (2005)

Article Chemistry, Multidisciplinary

Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids

AP Abbott et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Article Chemistry, Multidisciplinary

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