4.6 Article

Fast photoactuation of elastic crystals based on 3-(naphthalen-1-yl)-2-phenylacrylonitriles triggered by subtle photoisomerization

期刊

JOURNAL OF MATERIALS CHEMISTRY C
卷 10, 期 38, 页码 14273-14281

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2tc02667h

关键词

-

资金

  1. National Natural Science Foundation of China [51773076]
  2. Open Project of State Key Laboratory of Supramolecular Structure and Materials [SKLSSM2022011]

向作者/读者索取更多资源

A series of derivatives were synthesized through the Knoevenagel condensation reaction, and these molecular crystals exhibited significant photomechanical motions under UV irradiation. The rapid photoactuation induced by subtle photoisomerization might originate from the relatively large change in molecular width and strong intermolecular interactions. These crystals also showed photomechanical effects in water, suggesting their potential as actuators in various practical applications.
A series of (Z)-3-(naphthalen-1-yl)-2-phenylacrylonitrile derivatives have been synthesized via the Knoevenagel condensation reaction. The photoisomerization takes place in the molecular crystals, which triggers the crystals to bend backward from the light source rapidly. In particular, significant photomechanical motions are observed in the initial several seconds of UV irradiation, during which the conversion ratio from Z- to E-isomer is less than ca. 0.4%. Such fast photoactuation induced by subtle photoisomerization might originate from the relatively large change in the molecular width after the photochemical reaction and strong intermolecular interactions to amplify the deformation at the molecular level into the macroscopic mechanical motion of the crystals. Therefore, the crystals performed reversible photo-induced bending and unbending by turning around the irradiation directions more than 100 times on account of the retained crystal integrity during photoactuation and the good elasticity of the crystals. The needle-like crystals also exhibit photomechanical effects in water. Such photochemical reaction-powered photomechanical molecular crystals may be employed as actuators in many practical application scenarios.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据