Cross-linking enhanced room-temperature phosphorescence of carbon dots

Currently, there is a strong drive to discover alternative materials that exhibit room-temperature phosphorescence (RTP) for displays, bioimaging, and data security. Ideally, these materials should be nontoxic, cheap, and possess controllable photoluminescent properties. Carbon dots (CDs) possess each of these characteristics, but to date, less attention has been paid to their RTP mechanism. Herein, we synthesized a series of CDs by self-crosslinking and carbonization of precursor. The resultant CDs were luminescent and exhibited a bright, micro-second afterglow lifetime. To increase the RTP, a second microwave processing step was used to coat the CDs with polyvinyl alcohol (PVA), polyacrylamide (PAM), or tetraethyl orthosilicate (TEOS), producing CDs@PVA, CDs@PAM, and CDs@TEOS composites. The core-shell structure acted to enhance crosslinking at the surface of the CDs to boost the RTP, creating abundant energy levels for intersystem crossover. In situ X-ray photoelectron spectroscopy verified electron transfer during luminescence. Finally, we present a design rule that can be used to tune the quantum yields and RTP lifetime of CDs, based on the effective stabilization of triplet excited states through the extent and strength of cross-linking. This simple strategy provides a flexible route for guiding the further development of CDs with tailored RTP properties for various applications.

Automated summary

There is a growing interest in finding alternative materials with room-temperature phosphorescence (RTP) for various applications. Carbon dots (CDs) are found to possess the desired characteristics, and their RTP mechanism has been investigated in this study. By crosslinking and coating the CDs, their RTP properties can be enhanced. A design rule has also been proposed to tune the quantum yields and RTP lifetime of CDs. This finding provides a flexible route for developing CDs with tailored RTP properties.