期刊
MATERIALS HORIZONS
卷 9, 期 11, 页码 2893-2900出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2mh00635a
关键词
-
资金
- National Nature Science Foundation of China [21790050, 21790051]
- National Key Research and Development Project of China [2018YFA0703501]
- Key Program of the Chinese Academy of Sciences [QYZDY-SSW-SLH015]
An effective two-dimensional encapsulation strategy was used to prepare a high-performance fluorinated carbon cathode. The obtained cathode showed outstanding charge transport kinetics, lithium-ion diffusion dynamics, and improved voltage platform, battery rate performance, and energy density.
An effective and original strategy described as two-dimensional encapsulation is designed to prepare a high-performance fluorinated carbon cathode composed of a fluorinated carbon/graphdiyne heterostructure (CFx/GDY). The GDY layers of CFx/GDY strengthened the three-dimensional contacts between the CFx particles and additive, achieving outstanding charge transport kinetics and accelerating the lithium-ion diffusion dynamic behavior. The obtained electrodes exhibited a significantly enhanced voltage platform of similar to 2.5 V, improved battery rate performance (5C, 621.6 mA h g(-1)) and energy density with 2039.3 W h kg(-1). The excellent storage kinetics can be ascribed to the electronic structure modulation of fluorinated carbon from GDY, and the hierarchical porosity of GDY to create an effective, stable electron transfer and robust ion transportation. Our results demonstrated that two-dimensional GDY encapsulation has enormous potential in improving the performance of lithium primary batteries.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据