☆ 4.4 Review

Advances in Organic Electrochemical Synthesis

ACTA CHIMICA SINICA (2022)

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Review Chemistry, Multidisciplinary

Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis

Christian A. Malapit et al.

Summary: Synthetic organic electrosynthesis has made significant progress in recent decades, improving both selectivity and efficiency, and exploring new transformations and sustainable reactions. This review discusses the latest advances in combining electrochemistry and homogeneous transition-metal catalysis for organic synthesis, and explores future directions and challenges in the field.

CHEMICAL REVIEWS (2022)

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Article Multidisciplinary Sciences

Insertion of ammonia into alkenes to build aromatic N-heterocycles

Shuai Liu et al.

Summary: The authors demonstrate a novel methodology for the synthesis of aromatic heterocycles containing nitrogen by electrochemically inserting nitrogen atoms into a carbon ring using ammonia. This approach offers high atom and step economy, making it valuable for extensive applications in chemical and biological research, with significant potential for drug development.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Electrochemical Rhodium-Catalyzed Enantioselective C-H Annulation with Alkynes

Yuan-Qiong Huang et al.

Summary: The synergistic use of transition metal catalysis and electrochemistry is an attractive strategy for oxidative site-selective C-H functionalization. This study presents an electrochemically tuned rhodium-catalyzed enantioselective C-H annulation, which provides a practical and environmentally benign tool for the synthesis of chiral spiropyrazolones.

CCS CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

Recent Applications of Homogeneous Catalysis in Electrochemical Organic Synthesis

Xu Cheng et al.

Summary: This review presents recent advances in electrochemical homogeneous catalysis, with a focus on electrochemical noble-transition-metal catalysis, photoelectrochemical catalysis, and electrochemical enantioselective catalysis. The topics discussed include the mechanism of noble metal catalysts in the presence of cathodic hydrogen evolution, the enhancement of redox properties in photocatalysis, and the regulation of enantioselectivity in catalytic electrochemical reactions.

CCS CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

C-H Bond Functionalization under Electrochemical Flow Conditions

Tamlal Pokhrel et al.

Summary: This article provides a comprehensive review of the importance and applications of flow electrochemical C-H functionalization. The flow electrolysis process is sustainable, reducing the generation of by-products and improving selectivity. This technology is applicable for constructing C-C and C-X bonds, as well as for benzylic oxidation and synthesis of biologically active molecules.

CHEMICAL RECORD (2022)

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Review Chemistry, Multidisciplinary

Recent Advances in C(sp3)-C(sp3) and C(sp3)-C(sp2) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses

Aurelie Claraz et al.

Summary: This review provides an overview of the recent achievements in the construction of C(sp(3))-C(sp(3)) and C(sp(3))-C(sp(2)) bonds via cathodic reactions since 2017. It includes electrochemical reductions and convergent paired electrolyses. Cathodic processes, although less investigated, have the potential to enable alternative retrosynthetic disconnections and the discovery of new transformations.

ACS ORGANIC & INORGANIC AU (2022)

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Article Chemistry, Multidisciplinary

Nickel-Catalyzed N-Arylation of NH-Sulfoximines with Aryl Halides via Paired Electrolysis

Dong Liu et al.

Summary: A novel strategy using nickel catalysis and electrochemistry has been developed for the construction of sulfoximine derivatives, achieving excellent functional group tolerance and yield under mild reaction conditions. Preliminary mechanistic studies suggest that anodic oxidation of a Ni-II species is crucial for promoting the reductive elimination of a C-N bond from a resulting Ni-III species at room temperature.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Catalyst- and Reagent-Free Formal Aza-Wacker Cyclizations Enabled by Continuous-Flow Electrochemistry

Chong Huang et al.

Summary: This paper presents a catalyst- and reagent-free formal aza-Wacker type cyclization reaction for the synthesis of functionalized saturated N-heterocycles, conducted in a continuous-flow electrochemical reactor. The reactions exhibit broad tolerance of di-, tri-, and tetrasubstituted alkenes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Organic

Aminomethylation of Aryl Bromides by Nickel-Catalyzed Electrochemical Redox Neutral Cross Coupling

Yueyue Ma et al.

Summary: This method utilizes electrolysis processes, eliminating the need for a terminal oxidant, sacrificial anode, metal reductant, and prefunctionalized radical precursor. It shows broad functional group tolerance and provides a more environmentally friendly and synthetically practical approach for forming C(sp2)-C(sp3) bonds.

ORGANIC LETTERS (2021)

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Article Chemistry, Multidisciplinary

Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides

Zijian Li et al.

Summary: This method utilizes alcohols and aryl bromides as coupling partners, combining anodic preparation and nickel catalysis to efficiently construct C(sp(2))-C(sp(3)) bonds. The nickel-catalyzed paired electrolysis reaction showcases a broad substrate scope suitable for the synthesis of multifunctional compounds.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Electrochemical Oxidation Enables Regioselective and Scalable α-C(sp3)-H Acyloxylation of Sulfides

Huamin Wang et al.

Summary: A highly selective, environmentally friendly, and scalable electrochemical protocol for constructing alpha-acyloxy sulfides has been developed, utilizing the synergistic effect of self-assembly-induced C(sp(3))-H/O-H cross-coupling. This protocol demonstrates broad substrate scope, high regioselectivity, gram-scale synthesis, construction of complex molecules, and applicability to various nucleophiles. The pivotal role of substrate self-assembly has been confirmed through soft X-ray absorption technique and control experiments, contributing to the excellent compatibility and precise regioselectivity control in the electrochemical protocol.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Multidisciplinary Sciences

Merging shuttle reactions and paired electrolysis for reversible vicinal dihalogenations

Xichang Dong et al.

Summary: The study presents an electrochemically assisted shuttle (e-shuttle) paradigm for the facile and scalable interconversion of alkenes and vicinal dihalides, which can be used to synthesize dihalogenated molecules or recycle waste materials. The method demonstrates dibromination or dichlorination of alkenes using simple setup with inexpensive graphite electrodes. Additionally, it shows the complete dechlorination of hexachlorinated lindane to benzene using simple alkene acceptors in soil samples.

SCIENCE (2021)

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Article Multidisciplinary Sciences

Divergent rhodium-catalyzed electrochemical vinylic C-H annulation of acrylamides with alkynes

Yi-Kang Xing et al.

Summary: Alpha-pyridones and alpha-pyrones are common structural motifs in natural products and biologically active compounds. This study reports an oxidant-free Rh-catalyzed electrochemical vinylic C-H annulation of acrylamides with alkynes, providing alpha-pyridones and cyclic imidates through divergent pathways with excellent regioselectivities.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Organic Electrochemistry: Molecular Syntheses with Potential

Cuiju Zhu et al.

Summary: Organic electrosynthesis has emerged as a sustainable platform for molecular assembly, showcasing exceptional selectivities, synergies with photocatalysis or dual electrocatalysis, and novel mechanisms in metallaelectrocatalysis.

ACS CENTRAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Reaching the Full Potential of Electroorganic Synthesis by Paired Electrolysis

Wenzhao Zhang et al.

Summary: Electroorganic synthesis is a rapidly developing research area within organic synthesis, focusing on paired electrolysis for simultaneous oxidation and reduction reactions to maximize atom and energy efficiency.

CHEMICAL RECORD (2021)

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Review Chemistry, Multidisciplinary

Indirect Electrosynthesis with Halogen Ions as Mediators

Fei Lian et al.

Summary: Organic electrosynthesis using electric current as redox regents is a sustainable alternative to traditional methods. Indirect electrosynthesis with mediators lowers overpotentials for substrate activation, enhancing reaction efficiency and functional group compatibility. Electrochemical reactions utilizing halogen mediators have the potential to broaden their scope and contribute to future developments in electrosynthesis.

CHEMICAL RECORD (2021)

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Article Chemistry, Multidisciplinary

Green Chemistry: Electrochemical Organic Transformations via Paired Electrolysis

Najoua Sbei et al.

Summary: Paired electrolysis is a highly efficient green process that reduces energy and time consumption, benefiting resource preservation and waste reduction. However, compatibility between oxidation and reduction processes is crucial for achieving optimal products.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

TEMPO-Enabled Electrochemical Enantioselective Oxidative Coupling of Secondary Acyclic Amines with Ketones

Zhen-Hua Wang et al.

Summary: An electrochemical asymmetric coupling of secondary acyclic amines with ketones via Shono-type oxidation was achieved, resulting in good to excellent diastereoselectivity and enantioselectivity of the corresponding amino acid derivatives. The addition of an N-oxyl radical as a redox mediator allowed for selective oxidation of the substrate over the product, maintaining reaction selectivity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Applied

High-Throughput Electrochemistry: State of the Art, Challenges, and Perspective

Alfie G. Wills et al.

Summary: Electrochemical transformations involve complex interactions among various parameters, posing a challenge in developing robust and scale-independent reactions. High-throughput experimentation is a useful method for optimizing reactions and testing their robustness.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2021)

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Article Chemistry, Multidisciplinary

Unlocking the Potential of High-Throughput Experimentation for Electrochemistry with a Standardized Microscale Reactor

Jonas Rein et al.

Summary: Organic electrochemistry is becoming an important and sustainable technology in modern organic synthesis. The lack of general, standardized platforms for high-throughput experimentation has hindered the broad adoption of electrochemistry in the synthetic community and industrial settings. The HTe-Chem is a high-throughput microscale electrochemical reactor designed to accelerate reaction optimization, reaction discovery, and chemical library synthesis under various electrochemical conditions.

ACS CENTRAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Recent Advances in C(sp3)-C(sp3) and C(sp3)-C(sp2) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses

Aurelie Claraz et al.

Summary: This review provides an overview on recent achievements in the construction of C(sp3)-C(sp3) and C(sp3)-C(sp2) bonds via cathodic reactions since 2017, including electrochemical reductions and convergent paired electrolyses.

ACS ORGANIC & INORGANIC AU (2021)

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Article Chemistry, Multidisciplinary

Transition metal-catalyzed organic reactions in undivided electrochemical cells

Cong Ma et al.

Summary: Transition metal-catalyzed organic electrochemistry is a rapidly growing research area, with recent focus on transition metal-catalyzed paired electrolysis. Compared to conventional methods, this approach offers advantages in controlling reaction activity and selectivity and provides numerous opportunities for new and improved organic reaction methods in the future.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Recent advances in electrochemical oxidative cross-coupling with hydrogen evolution involving radicals

Yong Yuan et al.

Summary: Oxidative cross-coupling is a robust method for forming C-C, C-X, and X-Y bonds. Organic electrosynthesis is recognized as an environmentally friendly and powerful synthetic platform. Recent advancements have shown that radical-involved electrochemical oxidative cross-coupling reactions can be achieved under exogenous-oxidant-free conditions.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Multidisciplinary

Electrocatalysis as an enabling technology for organic synthesis

Luiz F. T. Novaes et al.

Summary: Electrochemistry has recently become a versatile strategy in achieving challenging transformations in synthetic organic chemistry. The use of redox-active electrocatalysts has increased in recent developments in electrosynthesis to enhance control over reactive intermediates. Electrocatalytic mediators allow for synthetic transformations to proceed in a manner different from purely chemical methods.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Electrochemistry Broadens the Scope of Flavin Photocatalysis: Photoelectrocatalytic Oxidation of Unactivated Alcohols

Wen Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Electrochemistry

Basic Strategies and Types of Applications in Organic Electrochemistry

Gerhard Hilt

CHEMELECTROCHEM (2020)

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Review Chemistry, Multidisciplinary

Electrochemical Oxidation of Organic Molecules at Lower Overpotential: Accessing Broader Functional Group Compatibility with Electron-Proton Transfer Mediators

Fei Wang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Review Chemistry, Multidisciplinary

A Decade of Electrochemical Dehydrogenative C,C-Coupling of Aryls

Johannes L. Roeckl et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Review Chemistry, Multidisciplinary

Anodic Oxidation for the Stereoselective Synthesis of Heterocycles

Kosuke Yamamoto et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Review Chemistry, Multidisciplinary

A Survival Guide for the Electro-curious

Cian Kingston et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Review Chemistry, Multidisciplinary

Site-Selective C-H Functionalization via Synergistic Use of Electrochemistry and Transition Metal Catalysis

Ke-Jin Jiao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Review Chemistry, Multidisciplinary

Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery

Juno C. Siu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Review Chemistry, Multidisciplinary

Synthetic Photoelectrochemistry

Joshua P. Barham et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Nickel-Catalyzed Electrochemical Reductive Relay Cross-Coupling of Alkyl Halides to Aryl Halides

Ke-Jin Jiao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Asymmetric Electrochemical Transformations

Xihao Chang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Nickel-Catalyzed Chain-Walking Cross-Electrophile Coupling of Alkyl and Aryl Halides and Olefin Hydroarylation Enabled by Electrochemical Reduction

Gadde Sathish Kumar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Electrophotocatalytic Undirected C-H Trifluoromethylations of (Het)Arenes

Youai Qiu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Article Chemistry, Analytical

Electrochemical synthesis of thiazoles from 2,5-dihydrothiazolines mediated by bromide/tetrachlorohydroquinone dual redox catalysts

Yong Li et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Potent Reductants via Electron-Primed Photoredox Catalysis: Unlocking Aryl Chlorides for Radical Coupling

Nicholas G. W. Cowper et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials

Hyunwoo Kim et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Electrophotocatalytic C-H Functionalization of Ethers with High Regioselectivity

He Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Electrophotocatalytic Decarboxylative C-H Functionalization of Heteroarenes

Xiao-Li Lai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

CuII/TEMPO-Catalyzed Enantioselective C(sp3)-H Alkynylation of Tertiary Cyclic Amines through Shono-Type Oxidation

Pei-Sen Gao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Enantioselective Pallada-Electrocatalyzed C-H Activation by Transient Directing Groups: Expedient Access to Helicenes

Uttam Dhawa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Biphasic Bioelectrocatalytic Synthesis of Chiral β-Hydroxy Nitriles

Fangyuan Dong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Enantioselective Ni-Catalyzed Electrochemical Synthesis of Biaryl Atropisomers

Hui Qiu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Merging Electrosynthesis and Bifunctional Squaramide Catalysis in the Asymmetric Detrifluoroacetylative Alkylation Reactions

Xihao Chang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Scalable Photoelectrochemical Dehydrogenative Cross-Coupling of Heteroarenes with Aliphatic C-H Bonds

Pin Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Catalytic Asymmetric Electrochemical α-Arylation of Cyclic β-Ketocarbonyls with Anodic Benzyne Intermediates

Longji Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry

Jinjian Liu et al.

ACS CENTRAL SCIENCE (2020)

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Review Chemistry, Multidisciplinary

Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

Hui Chen et al.

CHEMICAL REVIEWS (2020)

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Article Multidisciplinary Sciences

Microfluidic electrochemistry for single-electron transfer redox-neutral reactions

Yiming Mo et al.

SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Manganese-Catalyzed Oxidative Azidation of C(sp3)-H Bonds under Electrophotocatalytic Conditions

Linbin Niu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Review Chemistry, Multidisciplinary

Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?

Tjark H. Meyer et al.

CHEM (2020)

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Review Chemistry, Organic

Advances in Asymmetric Organotransition Metal-Catalyzed Electrochemistry

Xiangyang Wang et al.

CHINESE JOURNAL OF ORGANIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Electro-organic synthesis - a 21st century technique

Dennis Pollok et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C-H bonds

Lei Zhang et al.

CHEMICAL SCIENCE (2020)

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Review Chemistry, Multidisciplinary

3d metallaelectrocatalysis for resource economical syntheses

Parthasarathy Gandeepan et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Paired Electrochemical Reactions and the On-Site Generation of a Chemical Reagent

Tiandi Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp3)-H Bonds

Fei Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Continuous-Flow Electrosynthesis of Benzofused S-Heterocycles by Dehydrogenative C-S Cross-Coupling

Chong Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry

Dong Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Upgraded Bioelectrocatalytic N2 Fixation: From N2 to Chiral Amine Intermediates

Hui Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Organic

Palladium-Catalyzed Electrochemical C-H Bromination Using NH4Br as the Brominating Reagent

Qi-Liang Yang et al.

ORGANIC LETTERS (2019)

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Article Multidisciplinary Sciences

Scalable and safe synthetic organic electroreduction inspired by Li-ion battery chemistry

Byron K. Peters et al.

SCIENCE (2019)

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Article Chemistry, Physical

Electrochemically Promoted Nickel-Catalyzed Carbon-Sulfur Bond Formation

Yang Wang et al.

ACS CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Asymmetric Electrochemical Catalysis

Qifeng Lin et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

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Article Chemistry, Physical

Enantioselective Electroreductive Coupling of Alkenyl and Benzyl Halides via Nickel Catalysis

Travis J. DeLano et al.

ACS CATALYSIS (2019)

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Review Chemistry, Multidisciplinary

Electroorganic Synthesis under Flow Conditions

Mohamed Elsherbini et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

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Review Chemistry, Multidisciplinary

Electrochemical Oxidative Cross-Coupling with Hydrogen Evolution Reactions

Yong Yuan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

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Review Chemistry, Multidisciplinary

Chemistry with Electrochemically Generated N-Centered Radicals

Peng Xiong et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication

He Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Multidisciplinary

Direct Arylation of α-Amino C(sp3)-H Bonds by Convergent Paired Electrolysis

Yueyue Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Editorial Material Chemistry, Multidisciplinary

Merging Photocatalysis with Electrochemistry: The Dawn of a new Alliance in Organic Synthesis

Luca Capaldo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Organic

A review of asymmetric synthetic organic electrochemistry and electrocatalysis: concepts, applications, recent developments and future directions

Munmun Ghosh et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Electrochemistry-Enabled Ir-Catalyzed Vinylic C-H Functionalization

Qi-Liang Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Photoelectrochemical C-H Alkylation of Heteroarenes with Organotrifluoroborates

Hong Yan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Nitrogenase Bioelectrochemistry for Synthesis Applications

Ross D. Milton et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

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Article Chemistry, Inorganic & Nuclear

Palladium-Catalyzed Electrochemical C-H Alkylation of Arenes

Qi-Liang Yang et al.

ORGANOMETALLICS (2019)

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Article Multidisciplinary Sciences

Neuronal evidence for good-based economic decisions under variable action costs

Xinying Cai et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Decarboxylative [4+2] annulation of arylglyoxylic acids with internal alkynes using the anodic ruthenium catalysis

Mu-Jia Luo et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Palladium-Catalyzed ortho-Selective C-H Chlorination of Arenes Using Anodic Oxidation

Yang Qi-Liang et al.

ACTA CHIMICA SINICA (2019)

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Article Chemistry, Organic

Palladium-Catalyzed C-H Bond Acetoxylation via Electrochemical Oxidation

Anuska Shrestha et al.

ORGANIC LETTERS (2018)

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Review Chemistry, Multidisciplinary

Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions

Jordan E. Nutting et al.

CHEMICAL REVIEWS (2018)

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Article Chemistry, Multidisciplinary

Electrochemical Difluoromethylarylation of Alkynes

Peng Xiong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Organic

Electrochemical Formation of N-Acyloxy Amidyl Radicals and Their Application: Regioselective Intramolecular Amination of sp(2) and sp(3) C-H Bonds

Sheng Zhang et al.

ORGANIC LETTERS (2018)

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Review Chemistry, Physical

Recent Advances in C-H Functionalization Using Electrochemical Transition Metal Catalysis

Cong Ma et al.

ACS CATALYSIS (2018)

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Article Chemistry, Multidisciplinary

Synthesis of N-Heterocycles by Dehydrogenative Annulation of N-Allyl Amides with 1,3-Dicarbonyl Compounds

Zheng-Jian Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Multidisciplinary

Copper-Catalyzed Electrochemical C-H Amination of Arenes with Secondary Amines

Qi-Liang Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Multidisciplinary Sciences

Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles

Chen-Yan Cai et al.

NATURE COMMUNICATIONS (2018)

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Review Chemistry, Multidisciplinary

Use of Electrochemistry in the Synthesis of Heterocyclic Structures

Yangye Jiang et al.

CHEMICAL REVIEWS (2018)

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Review Chemistry, Multidisciplinary

Flow Electrolysis Cells for the Synthetic Organic Chemistry Laboratory

Derek Pletcher et al.

CHEMICAL REVIEWS (2018)

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Article Chemistry, Organic

Palladium-Catalyzed ortho-Selective C-H Chlorination of Benzamide Derivatives under Anodic Oxidation Conditions

Miki Konishi et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Palladium-Catalyzed C(sp3)-H Oxygenation via Electrochemical Oxidation

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Palladium-Catalyzed C(sp2)-H Acetoxylation via Electrochemical Oxidation

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ORGANIC LETTERS (2017)

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TEMPO-Catalyzed Electrochemical C-H Thiolation: Synthesis of Benzothiazoles and Thiazolopyridines from Thioamides

Xiang-Yang Qian et al.

ACS CATALYSIS (2017)

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Article Chemistry, Multidisciplinary

Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistry

Cong Ma et al.

CHEMICAL COMMUNICATIONS (2017)

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Review Chemistry, Multidisciplinary

Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance

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CHEMICAL REVIEWS (2017)

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Article Chemistry, Multidisciplinary

Synthesis of C3-Fluorinated Oxindoles through Reagent-Free Cross-Dehydrogenative Coupling

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Article Chemistry, Multidisciplinary

Electrochemical C-H/N-H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles

Zhong-Wei Hou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Multidisciplinary

Electrocatalytic Generation of Amidyl Radicals for Olefin Hydroamidation: Use of Solvent Effects to Enable Anilide Oxidation

Lin Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Multidisciplinary

Electroorganic synthesis of nitriles via a halogen-free domino oxidation-reduction sequence

Marius F. Hartmer et al.

CHEMICAL COMMUNICATIONS (2015)

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Review Chemistry, Multidisciplinary

Redox catalysis in organic electrosynthesis: basic principles and recent developments

Robert Francke et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Article Chemistry, Multidisciplinary

Total Synthesis of Dixiamycin B by Electrochemical Oxidation

Brandon R. Rosen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Chemistry, Multidisciplinary

A novel approach for the one-pot preparation of α-ketoamides by anodic oxidation

Zhenlei Zhang et al.

CHEMICAL COMMUNICATIONS (2013)

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Article Chemistry, Inorganic & Nuclear

Electrochemical Ortho Functionalization of 2-Phenylpyridine with Perfluorocarboxylic Acids Catalyzed by Palladium in Higher Oxidation States

Yulia B. Dudkina et al.

ORGANOMETALLICS (2013)

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Article Chemistry, Organic

MII/MIII-Catalyzed ortho-Fluoroalkylation of 2-Phenylpyridine

Yulia B. Dudkina et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2012)

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Article Chemistry, Organic

Catalytic Electrochemical C-H Iodination and One-Pot Arylation by ON/OFF Switching of Electric Current

Hiroko Aiso et al.

JOURNAL OF ORGANIC CHEMISTRY (2012)

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Article Chemistry, Multidisciplinary

Palladium-Catalyzed Aromatic C-H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation

Fumitoshi Kakiuchi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Article Chemistry, Applied

Electroenzymatic asymmetric reduction of rac-3-methylcyclohexanone to (1S,3S)-3-methylcyclohexanol in organic/aqueous media catalyzed by a thermophilic alcohol dehydrogenase

Volker Hoellrigl et al.

ADVANCED SYNTHESIS & CATALYSIS (2007)

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Article Chemistry, Applied

Electrochemical recycling of benzoquinone in the Pd/benzoquinone-catalyzed Heck-type reactions from arenes

Christian Amatore et al.

ADVANCED SYNTHESIS & CATALYSIS (2007)

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Article Chemistry, Multidisciplinary

Direct electrochemical regeneration of monooxygenase subunits for biocatalytic asymmetric epoxidation

F Hollmann et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

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Article Chemistry, Multidisciplinary

Anodic cyclization reactions: The total synthesis of alliacol A

J Mihelcic et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

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Article Chemistry, Organic

Chemical and electro-chemical reduction of qinghaosu (artemisinin)

WM Wu et al.

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (2000)

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