Hierarchically supramolecular polymerization of anthraquinone dye to chiral aggregates via 2D-monolayered nanosheets: the unanticipated role of pathway complexity

An anthraquinone dye underwent supramolecular polymerization, affording 2D-monolayered nanosheets in a kinetically controlled state. The nanosheets then transformed into hierarchically chiral aggregates in a thermodynamically controlled step. The unanticipated role played by pathway complexity was clearly unravelled in this work, highlighting the diversified pathways in the supramolecular polymerization of various building blocks.

Automated summary

This study reveals the unexpected role of pathway complexity in supramolecular polymerization and highlights the diversified pathways in the polymerization of different building blocks.