期刊
PHYSICAL REVIEW B
卷 106, 期 10, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.106.104103
关键词
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资金
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [447264071]
- European Union [881603]
This study presents a Raman investigation of MoS2 powders and MoS2 individual layers functionalized with organic molecules. It is found that the functionalized MoS2 powders are oxidized into MoO3 upon increasing temperature, while the mechanically exfoliated individual MoS2 layers do not undergo the same transformation. During the covalent functionalization, few-layer MoS2 undergoes a partial transition from the 2H to the 1T' crystallographic phase.
We present a Raman study of MoS2 powders and MoS2 individual layers covalently functionalized with organic molecules. In MoS2 powders, the defect-induced LA Raman mode shows evidence for successful functionalization. Increasing temperature induces oxidation of both functionalized and nonfunctionalized MoS2 into MoO3. In contrast, mechanically exfoliated individual MoS2 layers do not transfer into MoO3 under the same conditions. Instead, the Raman spectra show that the procedure of covalent functionalization leads to a partial transition from the 2H into the 1T' crystallographic phase in few-layer MoS2. We support the identification of the 1T' phase by DFT calculations of the corresponding vibrational modes in the mono-and bilayer 1T'-MoS2.
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