4.7 Article

Vacancy-enhanced oxygen redox and structural stability of spinel Li2Mn3O7-x

期刊

CHEMICAL COMMUNICATIONS
卷 58, 期 83, 页码 11685-11688

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc03259g

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资金

  1. National Natural Science Foundation of China [22075316, 22005334, 51972333]
  2. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB33030200]
  3. Youth Innovation Promotion Association of Chinese Academy of Sciences [2019009]

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Vacancies have a similar effect on the cathode materials of both Na-ion and Li-ion batteries.
Vacancies have been proved effective in activating the oxygen redox and stabilizing the structure of the oxide cathode materials for the Na-ion batteries, but their effect on the cathode materials of the Li-ion batteries is unclear. We herein show that they have similar effect on spinel [Li4/7Mn2/71/7](8a)[Li4/7Mn10/7](16d)[O4-x '](32e).

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