期刊
MINERALS
卷 6, 期 4, 页码 -出版社
MDPI AG
DOI: 10.3390/min6040126
关键词
PGE; PGM; fibrous; nanofibers; Ni-laterite; supergene; weathering; neoformation; Falcondo; Dominican Republic
资金
- FEDER Funds
- Spanish project [CGL2015-65824-P]
- Catalan project [2014-SGR-1661]
- Ministerio de Economia y Competitividad (Spain)
This contribution reports on the observation of enigmatic fibrous platinum-group minerals (PGM) found within a chromitite body included in limonite (floating chromitite) from Ni-laterites in the Dominican Republic. Fibrous PGM have a Ru-Os-Ir-Fe dominated composition and are characterized by fibrous textures explained by grain-forming fibers which are significantly longer (1-5 mu m) than they are wide (similar to 100 nm). Back-scattered electron (BSE) images suggest that these nanofibers are platinum-group elements (PGE)-bearing and form <5 mu m thick layers of bundles which are oriented orthogonal to grains' surfaces. Trace amounts of Si are most likely associated with PGE-bearing nanofibers. One characteristic fibrous PGM was studied in detail: XRD analyses point to ruthenian hexaferrum. However, the unpolished fibrous PGM shows numerous complex textures on its surface which are suggestive for neoformation processes: (i) features suggesting growth of PGE-bearing nanofibers; (ii) occurrence of PGM nanoparticles within film material (biofilm?) associated with PGE-bearing nanofibers; (iii) a Si-rich and crater-like texture hosting PGM nanoparticles and an Ir-rich accumulation of irregular shape; (iv) complex PGM nanoparticles with ragged morphologies, resembling sponge spicules and (v) oval forms (<1 mu m in diameter) with included PGM nanoparticles, similar to those observed in experiments with PGE-reducing bacteria. Fibrous PGM found in the limonite may have formed due to supergene (bio-)weathering of fibrous Mg-silicates which were incorporated into desulphurized laurite during stages of serpentinization.
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