期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 87, 页码 12172-12175出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc05196f
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资金
- Swiss National Science Foundation [175746]
- University of Basel
- NCCR Molecular Systems Engineering [182895]
- European Research Council (ERC) under the European Union [101002471]
- European Research Council (ERC) [101002471] Funding Source: European Research Council (ERC)
This study describes the deracemisation of fourfold stereogenic cobalt(III) diketonates using a chiral photocatalyst. An enantiomeric enrichment of up to 88:12 e.r. was achieved for the major meridional diastereomers with a low concentration of the photocatalyst, and a distribution of configurationally stable diastereomers distinct from the thermodynamic ratio was observed upon reaching the photostationary state.
The deracemisation of fourfold stereogenic cobalt(iii) diketonates with a chiral photocatalyst is described. With only 0.5 mol% menthyl Ru(bpy)(3)(2+) photocatalyst, an enantiomeric enrichment of up to 88 : 12 e.r. was obtained for the major meridional diastereomers. Moreover, a distribution of configurationally stable diastereomers distinct from the thermodynamic ratio was observed upon reaching the photostationary state.
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