Recent advances of NIR-TADF (λPL/ELmax > 700 nm) emitters and their applications in OLEDs

The rise of organic thermally activated delayed fluorescence (TADF) materials as NIR emitters and hosts have engrossed wide consideration as they can demonstrate 100% internal quantum efficiency. These materials have exceeded the phosphorescent noble-metal complexes due to cost-efficiency without compromising the OLED performance. Numerous applications of the NIR spectrum, e.g., in telecommunication, night-vision display, biomedical applications, and chemical sensors, render the NIR-TADF emitters vulnerable to evolution. This review highlights the various strategies adopted in the recent past (2015-2022) to judiciously design purely organic NIR-TADF emitters (lambda(max)(PL/EL) > 700 nm) with in-depth discussions of photophysical and device-electroluminescence studies. Approaches such as the incorporation of extended pi-conjugated acceptors, diazoles of group-16 elements, 'BF2'-acceptor, non-conjugated donor-acceptor dendrons, exciplex formation, and TADF sensitization provide effective pathways to construct high-efficiency NIR-TADF-OLEDs. Thus, this review aims to provide a new perspective for the next generation researchers to implement strategies for the thoughtful design of efficient NIR-TADF materials.

Automated summary

The rise of organic thermally activated delayed fluorescence (TADF) materials as NIR emitters and hosts has gained wide attention due to their capability of achieving 100% internal quantum efficiency. These materials outperform phosphorescent noble-metal complexes in terms of cost-efficiency without compromising OLED performance. The numerous applications of NIR-TADF emitters in the NIR spectrum, such as telecommunication and night-vision display, highlight the need for efficient design strategies. This review explores various approaches adopted in recent years to design high-efficiency purely organic NIR-TADF emitters.