4.6 Article

Exploring the influence of counterions on a hysteretic spin-transition in isomorphous iron(ii) complex salts

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Structural Insights into Hysteretic Spin-Crossover in a Set of Iron(II)-2,6-bis(1H-Pyrazol-1-yl)Pyridine) Complexes

Nithin Suryadevara et al.

Summary: This study investigates the structural facets of bistable spin-crossover complexes and their role in inducing hysteresis. Through single-crystal X-ray diffraction studies, it is found that molecular reorganizations and conformation switching contribute to the observed spin-state switching and hysteresis. These insights could potentially aid in the design of molecule-based switching and memory elements.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

Article Chemistry, Multidisciplinary

Four-Step Spin Crossover in a New Cyano-Bridged Iron-Silver Coordination Polymer

Olesia I. Kucheriv et al.

Summary: This article discusses the properties, structures, and potential applications of spin-crossover complexes with multistep transitions.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

Article Chemistry, Organic

The pKBHX Hydrogen-Bond Basicity Scale: From Molecules to Anions

Nicolas Galland et al.

Summary: The pKBHX hydrogen-bond basicity scale is extended to anionic HBAs, allowing the evaluation of anions' basicity. The scale is constructed through experimental measurements, linear free energy relationship estimations, and density functional theory calculations. The scale also reveals a correlation between the basicity of anions with unipolar substituents and the Hammett-Taft substituent constants Sigma.

JOURNAL OF ORGANIC CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

105 K Wide Room Temperature Spin Transition Memory Due to a Supramolecular Latch Mechanism

Maksym Seredyuk et al.

Summary: This study reports a new type of neutral Fe-II complex based on a novel asymmetric ligand. The complex forms a one-dimensional supramolecular chain due to its asymmetric shape in the lattice. The different spatial conformations of the 3-methoxy groups in the supramolecular arrangement have different effects on the spin transition process of the compound. It was found that one of the supramolecular arrangements can keep the compound in a high-spin state over a large temperature range.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Review Chemistry, Inorganic & Nuclear

Recent advances in ferroelectric metal complexes

Yoshihiro Sekine et al.

Summary: Ferroelectric materials possess spontaneous electric polarization that can be switched by an external electric field. They have abundant electrical, mechanical, and thermal properties, making them suitable for various functional devices. Ferroelectric materials based on coordination metal complexes have gained significant attention as they offer an efficient method for fabricating functional molecular materials.

COORDINATION CHEMISTRY REVIEWS (2022)

Article Materials Science, Multidisciplinary

Light-induced thermal hysteresis and high-spin low-spin domain formation evidenced by optical microscopy in a spin-crossover single crystal

Houcem Fourati et al.

Summary: The low-temperature photoinduced effects of the spin-crossover [{Fe(2-pytrz)(2)[Pd(CN)(4)]}]center dot 3H(2)O single crystal have been investigated. The results show that the system can be switched from an intermediate HS-LS state to a fully photoinduced LS state by irradiation in the near-infrared region. The study reveals that the LS state reached by light is a hidden stable state of the system until a certain temperature.

PHYSICAL REVIEW B (2022)

Review Chemistry, Multidisciplinary

Sublimable Spin-Crossover Complexes: From Spin-State Switching to Molecular Devices

Kuppusamy Senthil Kumar et al.

Summary: This review covers the advances in vacuum-sublimable SCO complexes, including the design and synthesis of functional SCO complexes, on-surface SCO of thin films, and various device architectures based on sublimable SCO complexes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Multiscale Approach of Spin Crossover Materials: A Concept Mixing Russian Dolls and Domino Effects

Philippe Guionneau et al.

Summary: The concept of multiscale understanding of SCO emphasizes the importance of considering structure-property relationships at different physical scales to fully grasp and take advantage of the phenomenon. This approach expands the range of potential applications, including the development of shape memory materials.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Multidisciplinary

The Atypical Hysteresis of [Fe(C6F5Tp)2]: Overlay of Spin-Crossovers and Symmetry-Breaking Phase Transition

Amina Benchohra et al.

Summary: The spin-crossover complex exhibits non-cooperative behavior and undergoes a symmetry-breaking phase transition when roughly 50% of the complexes are switched.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Spin-Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

Lalminthang Kipgen et al.

Summary: This article summarizes the research on spin-crossover molecules on solid surfaces in molecular spintronics, covering a range from single molecules to ultrathin films, mainly in the sub-10 nm range. The achievements, challenges, and prospects in this field are highlighted.

ADVANCED MATERIALS (2021)

Review Chemistry, Inorganic & Nuclear

Spin crossover and valence tautomerism conductors

Min Wang et al.

Summary: Research on multifunctional molecular materials with both magnetic bistability and electrical conductivity has expanded in the last two decades, providing materials with practical application prospects. This review presents recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials, as well as the synergistic and cooperative properties of bistability and conductivity.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Chemistry, Multidisciplinary

The number and shape of lattice solvent molecules controls spin-crossover in an isomorphous series of crystalline solvate salts

Izar Capel Berdiell et al.

Summary: The study investigated the structure and spin-transition behavior of compounds containing the [FeL2] group at low temperatures. When the ligand solvent is MeCN, the material's spin transition exhibits a hysteretic phenomenon, while in EtCN solvent the spin transition occurs in a two-step process.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Capturing photochemical and photophysical transformations in iron complexes with ultrafast X-ray spectroscopy and scattering

Kelly J. Gaffney

Summary: Light-driven chemical transformations offer a promising approach for advancing solar energy and catalysis applications, focusing on capturing non-equilibrium trajectories of electronic excited states and studying 3d metal complexes holds great potential. Recent advancements in ultrafast X-ray laser science have enabled detailed insights into electronic excited state dynamics in these complexes.

CHEMICAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Interplay between spin crossover and proton migration along short strong hydrogen bonds

Veronica Jornet-Molla et al.

Summary: This study found that iron(ii) salt compound exhibits different spin states at different temperatures, and the light-induced excited state affects proton motion, demonstrating complex and diverse interactions.

CHEMICAL SCIENCE (2021)

Review Nanoscience & Nanotechnology

Molecular magnetism: from chemical design to spin control in molecules, materials and devices

Eugenio Coronado

NATURE REVIEWS MATERIALS (2020)

Article Chemistry, Multidisciplinary

Elucidating the Structural Chemistry of a Hysteretic Iron(II) Spin-Crossover Compound From its Copper(II) and Zinc(II) Congeners

Christopher M. Pask et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Multidisciplinary

Heat Capacity and Thermal Damping Properties of Spin-Crossover Molecules: A New Look at an Old Topic

Karl Ridier et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Inorganic & Nuclear

Magnetocaloric and barocaloric effects of metal complexes for solid state cooling: Review, trends and perspectives

Mario S. Reis

COORDINATION CHEMISTRY REVIEWS (2020)

Article Chemistry, Multidisciplinary

X-Seed 4: updates to a program for small-molecule supramolecular crystallography

Leonard J. Barbour

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2020)

Review Chemistry, Inorganic & Nuclear

Spin crossover polymer composites, polymers and related soft materials

Alejandro Enriquez-Cabrera et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Article Chemistry, Inorganic & Nuclear

Spin Crossover in Iron(III) Quinolylsalicylaldiminates: The Curious Case of [Fe(qsal-F)(2)](Anion)

Raul Diaz-Torres et al.

INORGANIC CHEMISTRY (2020)

Article Materials Science, Multidisciplinary

4D printing with spin-crossover polymer composites

Mario Piedrahita-Bello et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

Article Chemistry, Multidisciplinary

Light- and temperature-assisted spin state annealing: accessing the hidden multistability

Yan-Cong Chen et al.

CHEMICAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Bistable molecular materials with dynamic structures

Zi-Shuo Yao et al.

CHEMICAL COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

The First Observation of Hidden Hysteresis in an Iron(III) Spin-Crossover Complex

Theerapoom Boonprab et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Slow Dynamics of the Spin-Crossover Process in an Apparent High-Spin Mononuclear FeII Complex

Yi Shan Ye et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Inorganic & Nuclear

Kinetic Trapping Effects in Amphiphilic Iron(II) Spin Crossover Compounds

Johannes Weihermueller et al.

INORGANIC CHEMISTRY (2019)

Review Chemistry, Inorganic & Nuclear

Spin-crossover in iron(ii)-Schiff base complexes

Kuppusamy Senthil Kumar et al.

DALTON TRANSACTIONS (2019)

Article Chemistry, Inorganic & Nuclear

Crystallinity and Microstructural Versatility in the Spin-Crossover Polymeric Material [Fe(Htrz)2(trz)](BF4)

Arnaud Grosjean et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Micromachining-Compatible, Facile Fabrication of Polymer Nanocomposite Spin Crossover Actuators

Maria D. Manrique-Juarez et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Chemistry, Multidisciplinary

Synthesis of Anion-Mixed Crystals of Assembled Complexes Bridged by 1,2-Bis(4-pyridyl)ethane and the Ligand Field of Fe(NCS)(NCBH3) Unit

Haruka Dote et al.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2018)

Article Chemistry, Multidisciplinary

Solvatomorphism-Induced 45 K Hysteresis Width in a Spin-Crossover Mononuclear Compound

Abdelhak Djemel et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Editorial Material Chemistry, Multidisciplinary

Preface and introduction

Jacqueline Zarembowitch et al.

COMPTES RENDUS CHIMIE (2018)

Article Chemistry, Multidisciplinary

Solvent modified spin crossover in an iron(III) complex: phase changes and an exceptionally wide hysteresis

Wasinee Phonsri et al.

CHEMICAL SCIENCE (2017)

Article Chemistry, Multidisciplinary

The role of symmetry breaking in the structural trapping of light-induced excited spin states

Rafal Kulmaczewski et al.

CHEMICAL COMMUNICATIONS (2017)

Review Chemistry, Inorganic & Nuclear

Emerging trends in spin crossover (SCO) based functional materials and devices

Kuppusamy Senthil Kumar et al.

COORDINATION CHEMISTRY REVIEWS (2017)

Review Chemistry, Multidisciplinary

Photoinduced Structural Dynamics of Molecular Systems Mapped by Time-Resolved X-ray Methods

Majed Chergui et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

Heterometallic FeIII/K Coordination Polymer with a Wide Thermal Hysteretic Spin Transition at Room Temperature

Soonchul Kang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Review Chemistry, Inorganic & Nuclear

Spin crossover in iron(III) complexes

David J. Harding et al.

COORDINATION CHEMISTRY REVIEWS (2016)

Article Multidisciplinary Sciences

Spin-Crossover Materials towards Microwave Radiation Switches

Olesia I. Kucheriv et al.

SCIENTIFIC REPORTS (2016)

Review Chemistry, Inorganic & Nuclear

Spin state behavior of iron(II)/dipyrazolylpyridine complexes. New insights from crystallographic and solution measurements

Laurence J. Kershaw Cook et al.

COORDINATION CHEMISTRY REVIEWS (2015)

Article Chemistry, Multidisciplinary

Easy Excited-State Trapping and Record High TTIESST in a Spin-Crossover Polyanionic FeII Trimer

Veronica Gomez et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Materials Science, Multidisciplinary

Cellulose-spin crossover particle composite papers with reverse printing performance: a proof of concept

V. Nagy et al.

JOURNAL OF MATERIALS CHEMISTRY C (2015)

Editorial Material Materials Science, Multidisciplinary

Spin-state switches in molecular materials chemistry

Shinya Hayami et al.

JOURNAL OF MATERIALS CHEMISTRY C (2015)

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

Review Chemistry, Multidisciplinary

Spin-crossover Compounds with Wide Thermal Hysteresis

Malcolm A. Halcrow

CHEMISTRY LETTERS (2014)

Article Chemistry, Multidisciplinary

Spin-State Ordering on One Sub-lattice of a Mononuclear Iron( III) Spin Crossover Complex Exhibiting LIESST and TIESST

Kevin D. Murnaghan et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

Review Chemistry, Inorganic & Nuclear

Spin state switching in 2,6-bis(pyrazol-3-yl)pyridine (3-bpp) based Fe(II) complexes

Gavin A. Craig et al.

COORDINATION CHEMISTRY REVIEWS (2014)

Article Chemistry, Multidisciplinary

Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

Thomas D. Roberts et al.

CHEMICAL COMMUNICATIONS (2013)

Article Chemistry, Inorganic & Nuclear

Multimetastability in a Spin-Crossover Compound Leading to Different High-Spin-to-Low-Spin Relaxation Dynamics

Gavin A. Craig et al.

INORGANIC CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Antagonism between Extreme Negative Linear Compression and Spin Crossover in [Fe(dpp)2(NCS)2]center dot py

Helena J. Shepherd et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Photomagnetism of a sym-cis-Dithiocyanato Iron(II) Complex with a Tetradentate N,N'-Bis(2-pyridylmethyl)1,2-ethanediamine Ligand

Jean-Francois Letard et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

Review Chemistry, Multidisciplinary

Structure:function relationships in molecular spin-crossover complexes

Malcolm A. Halcrow

CHEMICAL SOCIETY REVIEWS (2011)

Article Chemistry, Multidisciplinary

Coupled Crystallographic Order-Disorder and Spin State in a Bistable Molecule: Multiple Transition Dynamics

Gavin A. Craig et al.

CHEMISTRY-A EUROPEAN JOURNAL (2011)

Review Chemistry, Inorganic & Nuclear

Iron(II) complexes of 2,6-di(pyrazol-1-yl)pyridines-A versatile system for spin-crossover research

Malcolm A. Halcrow

COORDINATION CHEMISTRY REVIEWS (2009)

Article Chemistry, Multidisciplinary

Molecules embracing in crystals

Ian Dance et al.

CRYSTENGCOMM (2009)

Article Chemistry, Inorganic & Nuclear

Two-Step Spin-Transition Iron(III) Compound with a Wide [High Spin-Low Spin] Plateau

Jinkui Tang et al.

INORGANIC CHEMISTRY (2009)

Article Chemistry, Inorganic & Nuclear

One-Step and Two-Step Spin-Crossover Iron(II) Complexes of ((2-Methylimidazol-4-yl)methylidene)histamine

Tetsuya Sato et al.

INORGANIC CHEMISTRY (2009)

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

Article Chemistry, Multidisciplinary

An Iron(II) Spin-Crossover Complex with a 70 K Wide Thermal Hysteresis Loop

Birgit Weber et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

[Fe(sal(2)-trien)][Ni(dmit)(2)]: towards switchable spin crossover molecular conductors

S Dorbes et al.

CHEMICAL COMMUNICATIONS (2005)

Article Chemistry, Inorganic & Nuclear

A study of the electronic spin-state crossover in {Fe[HC(3,4,5-Me3pz)3]2}1(BF4)2

DL Reger et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2004)

Article Chemistry, Multidisciplinary

Thermal trapped iron(II) high spin state investigated by X-ray diffraction

M Marchivie et al.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2004)

Article Chemistry, Multidisciplinary

Iron(III) spin-crossover compounds with a wide apparent thermal hysteresis around room temperature

S Hayami et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)