期刊
ORGANIC CHEMISTRY FRONTIERS
卷 9, 期 23, 页码 6466-6474出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo01358d
关键词
-
资金
- National Natural Science Foundation of China [22101260]
- Natural Science Foundation of Zhejiang Province [LQ22B020001]
Researchers have reported a new host molecule that can regulate the aggregation behavior and fluorescence properties of PDI dyes in solid state through host-guest isolation. The host molecule, 1, demonstrates the ability to recognize different PDI dyes and significantly enhance their fluorescence.
Fluorescence quenching in solid state is a long-standing problem in dye chemistry, wherein perylene diimide (PDI) dyes are one of the trickiest classes of dyes due to their strong propensity of face-to-face self-aggregation. Here we report a new host molecule (1) that is capable of regulating the aggregation behaviour and fluorescence properties of various PDI dyes in solid state via host-guest isolation. Through UV-vis, NMR and fluorescence studies, we demonstrate for the first time the universality of a host, 1, in recognizing different PDI dyes. A simulated NMR structure based on NOE correlations provides the structural evidence of host-guest isolation. The ability of 1 to rescue the quenched fluorescence of PDI dyes in solid state is carefully verified by comparing UV-illuminated images and quantum yields of PDI + 1 with those of PDI alone. Remarkably, all the tested PDI dyes, with different sizes and diverse substituents, show greatly enhanced fluorescence after the addition of 1. Finally, after testing other popular hosts, the unique universality of 1 in rescuing the solid-state fluorescence of PDI dyes is shown.
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