期刊
RSC ADVANCES
卷 12, 期 47, 页码 30236-30247出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra05136b
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资金
- U.S. Department of Energy (DOE), the Office of Energy Efficiency & Renewable Energy (EERE) Awards [DE-EE0009257]
- Bioproducts, Science & Engineering Laboratory
- Department of Biological Systems Engineering at Washington State University
- University Grants Commission (UGC), India
Research found that Ni5Co5-AC catalyst on activated carbon showed the best catalytic performance due to its distorted metal alloy spinel structure and optimum particle size, enhancing its catalytic efficiency.
Catalytic hydrodeoxygenation (HDO) of anisole was performed with a series of Ni and Co containing catalysts with different weight ratios on activated carbon (AC) for cyclohexanol production. The catalytic activities of various catalysts revealed that Ni5Co5-AC was the best catalytic system. Structural analysis obtained from XRD, TPR, XPS, and TEM evidently demonstrates that Ni5Co5-AC sample consists of a distorted metal alloy spinel structure and optimum particle size, enhancing its catalytic performance. Kinetics were investigated to identify cyclohexanol production rate, activation energy, and reaction pathway. Structural, experimental, kinetics and density functional simulations suggested that high amount of distorted metallic alloy in Ni5Co5-AC, presence of water, high adsorption efficiency of anisole, and low adsorption tendency of cyclohexanol on metallic alloy surface were the critical factors for HDO of anisole to cyclohexanol.
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