期刊
NANOSCALE
卷 14, 期 46, 页码 17210-17221出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nr04407b
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资金
- National Natural Science Foundation of China [22262027]
- Singapore MOE Tier 1 [2020-T1-001-031]
- National First-rate Discipline Construction Project of Ningxia [NXYLXK2017A04]
- Ningxia Natural Science Foundation [22132003]
- College Students' Innovative and Entrepreneurship Training Program of Ningxia University, China [G2021107490015]
In this study, a mesoporous Bi-Ni bimetal nanosheet was prepared by a self-template electrochemical in situ process as an electrocatalyst, and it exhibited similar activity and stability to commercial Pt/C for efficient hydrogen generation through water electrolysis.
Active and durable electrocatalysts are very important for efficient and economically sustainable hydrogen generation via electrocatalytic water splitting. A bismuth-nickel (Bi-Ni) bimetal nanosheet with a mesoporous structure was prepared via a self-template electrochemical in situ process. The Bi-Ni catalyst required overpotentials of 56 mV and 183 mV at 10 mA cm(-2) for the hydrogen evolution reaction (HER), which were close to that of commercial Pt/C in 1.0 M KOH and 1.0 M PBS (pH 7.0), respectively. The electrocatalyst maintained a steady current density during 20 h electrolysis in 1.0 M KOH and 1.0 M PBS (pH 7.0). Density functional theory (DFT) indicated that the alloying effect could induce charge transfer from the Bi atom to Ni atom and thus modulate the d-band centre of Bi-Ni nanosheets, which could efficiently accelerate H* conversion and H-2 desorption at the Ni active site. This promotes the HER kinetics. By adopting the Bi84.8Ni15.2 alloy as the cathode to establish a full-cell (IrO2 parallel to Bi84.8Ni15.2) for water splitting in 1.0 M KOH, the required cell voltage was 1.53 V to drive 10 mA cm(-2), which was lower than that of the IrO2 parallel to Pt/C electrolyzer (1.64 V@10 mA cm(-2)).
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