A Peptide-Based Hydrogel for Adsorption of Dyes and Pharmaceuticals in Water Remediation

The removal of dyes and pharmaceuticals from water has become a major issue in recent years due to the shortage of freshwater resources. The adsorption of these pollutants through nontoxic, easy-to-make, and environmentally friendly adsorbents has become a popular topic. In this work, a tetrapeptide-pyrene conjugate was rationally designed to form hydrogels under controlled acidic conditions. The hydrogels were thoroughly characterized, and their performance in the adsorption of various dyes and pharmaceuticals from water was investigated. The supramolecular hydrogel efficiently adsorbed methylene blue (MB) and diclofenac (DCF) from water. The effect of concentration in the adsorption efficiency was studied, and results indicated that while the adsorption of MB is governed by the availability of adsorption sites, in the case of DCF, concentration is the driving force of the process. In the case of MB, the nature of the dye-hydrogel interactions and the mechanism of the adsorption process were investigated through UV-Vis absorption spectroscopy. The studies proved how this dye is first adsorbed as a monomer, probably through electrostatic interactions; successively, at increasing concentrations as the electrostatic adsorption sites are depleted, dimerization on the hydrogel surface occurs.

Automated summary

The removal of dyes and pharmaceuticals from water is a critical issue due to freshwater scarcity. In this study, a tetrapeptide-pyrene conjugate was designed to form hydrogels, which efficiently adsorbed methylene blue and diclofenac. The concentration was found to affect the adsorption efficiency.