4.6 Review

Current Status of Formulations and Scalable Processes for Producing Sulfidic Solid-State Batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Nanoscience & Nanotechnology

Enhancing Moisture and Electrochemical Stability of the Li5.5PS4.5Cl1.5 Electrolyte by Oxygen Doping

Linfeng Peng et al.

Summary: This research successfully synthesized O-substituted Li5.5PS4.5-xOxCl1.5 solid electrolytes, among which Li5.5PS4.425O0.075Cl1.5 exhibits high ionic conductivity, improved moisture resistance, and enhanced electrochemical stability in higher voltage windows. Solid-state batteries using Li5.5PS4.425O0.075Cl1.5 show higher capacities and superior cyclability when operated at a high end-of-charge voltage, and exhibit outstanding performance in a wide temperature range.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Nanoscience & Nanotechnology

Hydrolysis of Argyrodite Sulfide-Based Separator Sheets for Industrial All-Solid-State Battery Production

Celestine Singer et al.

Summary: Researchers have studied the formation of harmful gas H2S when solid sulfide electrolytes come in contact with water. By analyzing exemplary material states, they found that water content has the highest impact on H2S formation rate, while other parameters have negligible effects. The study highlights the need for a controlled atmosphere in production facilities to ensure worker safety and product quality.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Engineering, Chemical

Characterization of solid-electrolyte/active-material composite particles with different surface morphologies for all-solid-state batteries

Eiji Hayakawa et al.

Summary: This study investigates the effects of the surface morphologies of composite particles on the performance of all-solid-state lithium-ion batteries (ASS-LIBs). The surface morphologies of the composite particles changed from discrete to continuous through dry coating. The cell prepared with composite particles showed higher ionic conductivity and lower internal resistance compared to the cell prepared with a simple mixture. Cells prepared with discrete-coating particles exhibited the highest charge capability, while those prepared with continuous-coating particles showed the highest discharge capability.

ADVANCED POWDER TECHNOLOGY (2022)

Article Materials Science, Multidisciplinary

Systematic evaluation of materials and recipe for scalable processing of sulfide-based solid-state batteries

Mattis Batzer et al.

Summary: Sulfide-based solid-state batteries have advantages over conventional lithium ion batteries, but face challenges in large-scale processing. This study focuses on a scalable solvent-based process to produce sulfide solid-state cathodes and separators. The composition of the slurries was systematically varied to investigate the impact on the mechanical and electrochemical properties. The best compositions were chosen for full cell assembly and cycling experiments, showing high active material utilization and coulombic efficiency.

MATERIALS TODAY COMMUNICATIONS (2022)

Review Chemistry, Physical

Scaling up high-energy-density sulfidic solid-state batteries: A lab-to-pilot perspective

Darren H. S. Tan et al.

Summary: Significant progress has been made in the field of all-solid-state batteries (ASSBs) in recent years, but there are still many technical challenges to overcome before commercialization. The key challenge lies in transitioning from laboratory-scale to pilot-scale production. Current research is often limited to form factors that are impractical for actual device operation. This article provides a perspective on the scalability challenges and considerations for ASSBs, and offers baseline fabrication and evaluation protocols. It also discusses the importance of bridging the development gap between university-level research and industry-scale production through collaboration with national laboratories.
Review Chemistry, Multidisciplinary

Lithium/Sulfide All-Solid-State Batteries using Sulfide Electrolytes

Jinghua Wu et al.

Summary: All-solid-state lithium batteries (ASSLBs) are considered the next generation electrochemical energy storage devices due to their high safety and energy density, along with simple packaging and wide operable temperature range. The sulfide electrolytes, with the highest ionic conductivity among solid-state electrolytes, face challenges such as narrow electrochemical stability window, unstable electrode/electrolyte interfaces, and lithium dendrite formation. Research on emerging sulfide electrolytes and preparation methods is ongoing, focusing on achieving required properties for stable electrochemical performance and compatible interfaces in ASSLBs.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Interfacial challenges for all-solid-state batteries based on sulfide solid electrolytes

Shuo Wang et al.

Summary: Sulfide solid electrolytes have the highest room-temperature ionic conductivity among solid Li-ion conductors, making them attractive for high energy-density and safe all-solid-state batteries. However, interfacial issues between sulfide electrolytes and electrodes, such as instability and side reactions, pose challenges for their application in ASSBs.

JOURNAL OF MATERIOMICS (2021)

Article Energy & Fuels

Sustainable Solvent-Free Production and Resulting Performance of Polymer Electrolyte-Based All-Solid-State Battery Electrodes

Laura Helmers et al.

Summary: Research suggests that by adjusting granulation process parameters, production time and costs can be reduced, while the solid polymer electrolyte distribution induced by the process has a significant influence on the rate capability of all-solid-state batteries.

ENERGY TECHNOLOGY (2021)

Article Chemistry, Physical

The Working Principle of a Li2CO3/LiNbO3 Coating on NCM for Thiophosphate-Based All-Solid-State Batteries

Felix Walther et al.

Summary: This study improves the performance of all-solid-state batteries (ASSBs) by using a Li2CO3/LiNbO3 coating, which suppresses the interfacial reaction between the cathode active material and solid electrolyte, leading to a significant enhancement in battery performance.

CHEMISTRY OF MATERIALS (2021)

Review Materials Science, Multidisciplinary

Challenges in Ecofriendly Battery Recycling and Closed Material Cycles: A Perspective on Future Lithium Battery Generations

Stefan Doose et al.

Summary: With the introduction of new generations of lithium batteries in the market, the recycling process chains, safety, and closed material cycles face greater challenges. Proper separation of different battery types and the adoption of flexible and highly sophisticated recycling processes are necessary to address these challenges.

METALS (2021)

Review Energy & Fuels

Post-lithium-ion battery cell production and its compatibility with lithium-ion cell production infrastructure

Fabian Duffner et al.

Summary: This review highlights the current production status of representative PLIBs and the advantages of lithium-ion batteries as advanced electrochemical energy storage technology. It also discusses the research and manufacturing processes of post-lithium technologies.

NATURE ENERGY (2021)

Article Materials Science, Multidisciplinary

Chemical stability of Li4PS4I solid electrolyte against hydrolysis

Marcela Calpa et al.

Summary: The chemical stability of Li4PS4I solid electrolyte was investigated under ambient atmosphere and compared with Li3PS4, showing effective suppression of H2S gas generation and good structural reversibility attributed to LiI incorporation. The solid electrolyte exhibited consistent ionic conductivity at room temperature before and after exposure to ambient atmosphere.

APPLIED MATERIALS TODAY (2021)

Article Chemistry, Physical

Single- or Poly-Crystalline Ni-Rich Layered Cathode, Sulfide or Halide Solid Electrolyte: Which Will be the Winners for All-Solid-State Batteries?

Yoonjae Han et al.

Summary: The use of single-crystalline NCA and oxidation-tolerable Li3YCl6 in all-solid-state batteries shows promising results in terms of discharge capacity, initial Coulombic efficiency, cycling performance, and rate capability. The overlooked contribution of side reactions to the degradation of polycrystalline NCA is revealed for the first time in this study through rigorous characterization and analysis.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

Issues and Advances in Scaling up Sulfide-Based All-Solid-State Batteries

Jieun Lee et al.

Summary: All-solid-state batteries are considered the next-generation energy storage concept, focusing on sulfide-based solid electrolytes for their high ionic conductivity and deformability. However, challenges such as air instability and electrode fabrication remain, with recent research efforts aimed at addressing these issues through novel materials and processing techniques.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Article Chemistry, Physical

Sheet-type all-solid-state batteries with sulfidic electrolytes: Analysis of kinetic limitations based on a cathode morphology study

Moritz Kroll et al.

Summary: All-solid-state batteries with sulfide-based solid electrolytes have the potential to increase the energy density of future Li-ion batteries. Differences in morphology and intrinsic ionic conductivity of the solid electrolytes can impact battery performance. A study on the cathodes of two ASSBs revealed that reducing charge transfer resistance at the cathode-solid electrolyte interface is crucial for improving battery performance.

JOURNAL OF POWER SOURCES (2021)

Article Electrochemistry

Increased Moisture Uptake of NCM622 Cathodes after Calendering due to Particle Breakage

Fabienne Huttner et al.

Summary: The study revealed that cathodes with higher densities have larger surface areas, leading to increased moisture uptake, but affecting ionic conductivity and causing capacity loss at higher rates.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Review Chemistry, Physical

Energy Storage Materials for Solid-State Batteries: Design by Mechanochemistry

Roman Schlem et al.

Summary: This review discusses the physical and mechanochemical processes that influence the processing of solid-state batteries, with a focus on the influence of milling and dispersing procedures on the ionic transport properties. By combining theoretical backgrounds with a wide range of examples, a better understanding of critical parameters related to mechanical milling of solid electrolytes and solid-state battery components is provided.

ADVANCED ENERGY MATERIALS (2021)

Article Energy & Fuels

Continuous Processing of Cathode Slurry by Extrusion for Lithium-Ion Batteries

Matthias Haarmann et al.

Summary: This study investigates the continuous mixing process for lithium-ion battery electrodes, exploring the impact of different material compositions and processing parameters on electrode performance, providing new insights into the process-structure-property relations of the mixing process.

ENERGY TECHNOLOGY (2021)

Article Chemistry, Multidisciplinary

Toward Practical Solid-State Lithium-Sulfur Batteries: Challenges and Perspectives

Saneyuki Ohno et al.

Summary: Solid-state lithium-sulfur batteries offer high energy density and safety benefits by using sulfur as conversion-type material, but challenges include overcoming contact losses caused by volume changes of active materials and complexities in composite materials.

ACCOUNTS OF MATERIALS RESEARCH (2021)

Article Chemistry, Multidisciplinary

Design-of-experiments-guided optimization of slurry-cast cathodes for solid-state batteries

Jun Hao Teo et al.

Summary: The study used a design of experiments (DoE) approach to evaluate the influence of polymer binder and conductive carbon additive on SSB cells, discovering that the optimized combination can enhance electrochemical performance and processability.

CELL REPORTS PHYSICAL SCIENCE (2021)

Article Electrochemistry

Design of Vacuum Post-Drying Procedures for Electrodes of Lithium-Ion Batteries

Fabienne Huttner et al.

Summary: In order to reduce residual moisture in lithium-ion batteries, electrodes and separators need to be post-dried before assembly. Careful selection of post-drying parameters is essential to reduce moisture without damaging the microstructure, while maintaining efficiency and cost effectiveness.

BATTERIES & SUPERCAPS (2021)

Review Electrochemistry

Electrolyte/Electrode Interfaces in All-Solid-State Lithium Batteries: A Review

Yuepeng Pang et al.

Summary: All-solid-state lithium batteries have great potential for higher energy density and safety, but the poor electrode compatibility of solid electrolytes may cause electrolyte/electrode interface degradation, leading to battery failure. Mechanistic analyses and strategies for enhancing electrolyte/electrode interfaces are crucial for the future development of these batteries.

ELECTROCHEMICAL ENERGY REVIEWS (2021)

Review Chemistry, Physical

Solid-State Li-Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces

Kun Joong Kim et al.

Summary: The introduction of new, safe, and reliable solid-electrolyte chemistries and technologies can potentially overcome the challenges facing their liquid counterparts while widening the breadth of possible applications. Through analyzing the transition from liquid-based Li-ion batteries (LIBs) to all-solid-state Li-metal batteries (ASSLBs), a roadmap for the development of a successful oxide and sulfide-based ASSLB is introduced, focusing on interfacial challenges and considering parameters such as energy density, power density, longterm stability, processing, and safety.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Stack Pressure Considerations for Room-Temperature All-Solid-State Lithium Metal Batteries

Jean-Marie Doux et al.

ADVANCED ENERGY MATERIALS (2020)

Article Nanoscience & Nanotechnology

Modeling Effective Ionic Conductivity and Binder Influence in Composite Cathodes for All-Solid-State Batteries

Anja Bielefeld et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Physical

Preparation of ambient air-stable electrolyte Li4SnS4 by aqueous ion-exchange process

Reiko Matsuda et al.

SOLID STATE IONICS (2020)

Article Engineering, Environmental

Novel dry deposition of LiNbO3 or Li2ZrO3 on LiNi0.6Co0.2Mn0.2O2 for high performance all-solid-state lithium batteries

Young-Jin Kim et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Energy & Fuels

Benchmarking the performance of all-solid-state lithium batteries

Simon Randau et al.

NATURE ENERGY (2020)

Review Chemistry, Multidisciplinary

Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries

Thorben Krauskopf et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

Stress distribution in the composite electrodes of sulfide all-solid-state lithium-ion batteries

Akinari Ohashi et al.

JOURNAL OF POWER SOURCES (2020)

Review Electrochemistry

Review-Knowledge-Based Process Design for High Quality Production of NCM811 Cathodes

Carina Amata Heck et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

Article Chemistry, Physical

Problems and their origins of Ni-rich layered oxide cathode materials

Sheng S. Zhang

ENERGY STORAGE MATERIALS (2020)

Article Materials Science, Multidisciplinary

Rational Design of Quasi-Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

Florian Strauss et al.

ACS MATERIALS LETTERS (2020)

Article Chemistry, Physical

Pressure effects on sulfide electrolytes for all solid-state batteries

Jean-Marie Doux et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Pressure-Driven Interface Evolution in Solid-State Lithium Metal Batteries

Xin Zhang et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

Review Electrochemistry

Solid-State Lithium Batteries: Bipolar Design, Fabrication, and Electrochemistry

Kyu-Nam Jung et al.

CHEMELECTROCHEM (2019)

Review Materials Science, Multidisciplinary

Powder aerosol deposition method - novel applications in the field of sensing and energy technology

Michaela Schubert et al.

FUNCTIONAL MATERIALS LETTERS (2019)

Article Chemistry, Physical

Microstructural Modeling of Composite Cathodes for All-Solid-State Batteries

Anja Bielefeld et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

Article Electrochemistry

Electrochemical Properties of Composite Cathode Using Bimodal Sized Electrolyte for All-Solid-State Batteries

Chanhwi Park et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

Review Materials Science, Multidisciplinary

Recent achievements on sulfide-type solid electrolytes: crystal structures and electrochemical performance

Ze Ma et al.

JOURNAL OF MATERIALS SCIENCE (2018)

Article Nanoscience & Nanotechnology

Degradation Mechanisms at the Li10GeP2S12/LiCoO2 Cathode Interface in an All-Solid-State Lithium-Ion Battery

Wenbo Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Chemo-mechanical expansion of lithium electrode materials - on the route to mechanically optimized all-solid-state batteries

Raimund Koerver et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

All-solid-state lithium-ion and lithium metal batteries - paving the way to large-scale production

Joscha Schnell et al.

JOURNAL OF POWER SOURCES (2018)

Article Chemistry, Physical

Impact of Cathode Material Particle Size on the Capacity of Bulk-Type All-Solid-State Batteries

Florian Strauss et al.

ACS ENERGY LETTERS (2018)

Article Nanoscience & Nanotechnology

Facile Synthesis toward the Optimal Structure-Conductivity Characteristics of the Argyrodite Li6PS5Cl Solid-State Electrolyte

Chuang Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Physical

Gas Evolution in All-Solid-State Battery Cells

Timo Bartsch et al.

ACS ENERGY LETTERS (2018)

Article Materials Science, Ceramics

Favorable composite electrodes for all-solid-state batteries

Atsushi Sakuda

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN (2018)

Article Electrochemistry

Slurry-Based Processing of Solid Electrolytes: A Comparative Binder Study

Nathalie Riphaus et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

Article Engineering, Industrial

Characterization of the calendering process for compaction of electrodes for lithium-ion batteries

Chris Meyer et al.

JOURNAL OF MATERIALS PROCESSING TECHNOLOGY (2017)

Article Electrochemistry

Selection of Binder and Solvent for Solution-Processed All-Solid-State Battery

Kyulin Lee et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

Article Electrochemistry

All-Solid-State Battery Electrode Sheets Prepared by a Slurry Coating Process

Atsushi Sakuda et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

Article Materials Science, Multidisciplinary

Mercury intrusion for ion- and conversion-based battery electrodes - Structure and diffusion coefficient determination

Linus Froboese et al.

MATERIALS CHARACTERIZATION (2017)

Review Nanoscience & Nanotechnology

Reviving the lithium metal anode for high-energy batteries

Dingchang Lin et al.

NATURE NANOTECHNOLOGY (2017)

Article Chemistry, Physical

Redox-active cathode interphases in solid-state batteries

Raimund Koerver et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Nanoscience & Nanotechnology

The Detrimental Effects of Carbon Additives in Li10GeP2S12-Based Solid-State Batteries

Wenbo Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

High Energy Batteries What you need for a Super-Battery?

Peter Bieker et al.

CHEMIE IN UNSERER ZEIT (2016)

Article Energy & Fuels

Life Cycle Assessment and resource analysis of all-solid-state batteries

Stefanie Troy et al.

APPLIED ENERGY (2016)

Editorial Material Energy & Fuels

A solid future for battery development

Juergen Janek et al.

NATURE ENERGY (2016)

Article Energy & Fuels

High-power all-solid-state batteries using sulfide superionic conductors

Yuki Kato et al.

NATURE ENERGY (2016)

Article Materials Science, Ceramics

Effect of hybrid conductive additives on all-solid-state lithium batteries using Li2S-P2S5 glass-ceramics

Sungbo Hong et al.

CERAMICS INTERNATIONAL (2015)

Review Chemistry, Multidisciplinary

Issues and Challenges for Bulk-Type All-Solid-State Rechargeable Lithium Batteries using Sulfide Solid Electrolytes

Yoon Seok Jung et al.

ISRAEL JOURNAL OF CHEMISTRY (2015)

Article Engineering, Electrical & Electronic

Discontinuous and Continuous Processing of Low-Solvent Battery Slurries for Lithium Nickel Cobalt Manganese Oxide Electrodes

Henning Dreger et al.

JOURNAL OF ELECTRONIC MATERIALS (2015)

Article Chemistry, Physical

Solid Electrolyte: the Key for High-Voltage Lithium Batteries

Juchuan Li et al.

ADVANCED ENERGY MATERIALS (2015)

Article Chemistry, Physical

A synthesis of crystalline Li7P3S11 solid electrolyte from 1,2-dimethoxyethane solvent

Seitaro Ito et al.

JOURNAL OF POWER SOURCES (2014)

Review Pharmacology & Pharmacy

Genotoxicity and carcinogenicity risk of carbon nanotubes

Shinya Toyokuni

ADVANCED DRUG DELIVERY REVIEWS (2013)

Article Chemistry, Multidisciplinary

Li10SnP2S12: An Affordable Lithium Superionic Conductor

Philipp Bron et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Multidisciplinary Sciences

Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery

Atsushi Sakuda et al.

SCIENTIFIC REPORTS (2013)

Article Chemistry, Physical

Improvement of chemical stability of Li3PS4 glass electrolytes by adding MxOy (M = Fe, Zn, and Bi) nanoparticles

Akitoshi Hayashi et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

Review Materials Science, Ceramics

Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries

Masahiro Tatsumisago et al.

JOURNAL OF ASIAN CERAMIC SOCIETIES (2013)

Proceedings Paper Electrochemistry

Intensive Dry and Wet Mixing Influencing the Structural and Electrochemical Properties of Secondary Lithium-Ion Battery Cathodes

H. Bockholt et al.

LITHIUM-ION BATTERIES -AND- NON-AQUEOUS ELECTROLYTES FOR LITHIUM BATTERIES - PRIME 2012 (2013)

Article Materials Science, Multidisciplinary

Performance Optimization of All-Solid-State Lithium Ion Batteries Using a Li2S-P2S5 Solid Electrolyte and LiCoO2 Cathode

Junghoon Kim et al.

ELECTRONIC MATERIALS LETTERS (2012)

Article Materials Science, Multidisciplinary

Invited Paper: Recent Development of Bulk-Type Solid-State Rechargeable Lithium Batteries with Sulfide Glass-ceramic Electrolytes

Akitoshi Hayashi et al.

ELECTRONIC MATERIALS LETTERS (2012)

Article Electrochemistry

Variation in structure and Li+-ion migration in argyrodite-type Li6PS5X (X = Cl, Br, I) solid electrolytes

Prasada Rao Rayavarapu et al.

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2012)

Article Chemistry, Physical

Interfacial phenomena in solid-state lithium battery with sulfide solid electrolyte

Kazunori Takada et al.

SOLID STATE IONICS (2012)

Article Electrochemistry

How Electrolytes Influence Battery Safety

E. Peter Roth et al.

ELECTROCHEMICAL SOCIETY INTERFACE (2012)

Article Materials Science, Ceramics

Crystallization Process for Superionic Li7P3S11 Glass-Ceramic Electrolytes

Keiichi Minami et al.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2011)

Article Chemistry, Physical

A lithium superionic conductor

Noriaki Kamaya et al.

NATURE MATERIALS (2011)

Article Chemistry, Physical

Structural change of Li2S-P2S5 sulfide solid electrolytes in the atmosphere

Hiromasa Muramatsu et al.

SOLID STATE IONICS (2011)

Article Chemistry, Physical

Crystal structure and phase transitions of the lithium ionic conductor Li3PS4

Kenji Homma et al.

SOLID STATE IONICS (2011)

Article Chemistry, Physical

Crystal structure of a superionic conductor, Li7P3S11

Hisanori Yamane et al.

SOLID STATE IONICS (2007)

Article Electrochemistry

5 V class all-solid-state composite lithium battery with Li3PO4 coated LiNi0.5Mn1.5O4

Y Kobayashi et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2003)