期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 24, 期 43, 页码 26485-26498出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cp04200b
关键词
-
The phase boundaries and thermodynamic properties of crystal phases in the SA-AA system were studied experimentally. Different crystalline phases and solid solutions were identified, and their physical properties, such as solubility enhancements, were compared to the pure components. The thermodynamic relationships and phase transitions of the system were also analyzed.
The phase boundaries and thermodynamic properties of crystal phases in the salicylic acid (SA) - anthranilic acid (AA) system have been determined experimentally. The complete binary T-X diagram reveals a total of four crystalline phases, including a co-crystal and three crystalline solid solutions. The two eutectics were determined through triplicate DSC analyses at 33 compositions. By adding a liquid solvent and generating a ternary phase diagram, a methodology is introduced to determine the solid-state miscibility limits of the solid solutions at 20 and 55 degrees C. The crystalline solid solutions exhibit substantial differences in physical properties relative to the pure components, including solubility enhancements that are relevant for chemical processing and material properties. The thermodynamic relationships of the three polymorphs of AA have been resolved showing an enantiotropic transition temperature of 50-55 degrees C between Form I and III of pure AA. However, as a result of the solid solutions with SA, the enantiotropic transition temperature was suppressed by around 30 degrees C at the eutectoid. In addition, a co-existence envelope is formed, wherein the two AA polymorph solid solutions exist in equilibrium with one another over a wide range of temperatures and compositions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据