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Hierarchically Porous Metal-Organic Frameworks: Synthetic Strategies and Applications

SMALL STRUCTURES (2022)

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Summary: Hierarchically porous metal-organic frameworks (HP-MOFs) with macro-meso-micropores were efficiently constructed using a template-assisted spray drying followed by etching process. The method allows for easy adjustment of macropore and mesopore structures by altering the size and proportion of the template. The catalytic properties of HP-ZIF-8 in Knoevenagel reaction were significantly improved compared to microsized ZIF-8.

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