Possible absence of a Jahn-Teller distortion critical thickness in geometrically designed LaMnO3 films

We investigated the Jahn-Teller phonon modes in LaMnO3 film grown on an orthorhombic (110)-oriented GdScO3 substrate using Raman spectroscopy, which enabled us to verify the presence of the cooperative Jahn-Teller distortion in the ultrathin limit. A characteristic B1g phonon mode with preserved symmetry was observed down to the two-unit-cell thickness. This finding suggests the absence of a film-thickness-driven critical transition of the cooperative Jahn-Teller distortion and the corresponding orbital order when the two-dimensional Jahn-Teller-distortion plane is designed to be parallel to the substrate by misfit strain.

Automated summary

We investigated the presence of cooperative Jahn-Teller distortion in LaMnO3 films grown on GdScO3 substrates using Raman spectroscopy. We observed a characteristic B1g phonon mode with preserved symmetry down to a two-unit-cell thickness, suggesting that there is no critical transition of the cooperative Jahn-Teller distortion and corresponding orbital order driven by film thickness when the two-dimensional distortion plane is parallel to the substrate.