期刊
DOKLADY CHEMISTRY
卷 504, 期 2, 页码 106-117出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0012500822600080
关键词
C-C cross-coupling; solvent; bio-Profile; toxicity; ionic liquid
资金
- Russian Science Foundation (RSF) [21-13-00049]
This work investigates the contribution of different solvents to the overall cytotoxicity of chemical reactions using bio-Profiles and bio-Factors, with the synthesis of 1,1'-biphenyl as an example. The analyzed solvents include ethanol, N-methylpyrrolidone, and four ionic liquids.
In this work, we used a recently proposed concept of bio-Profiles and bio-Factors for studying the solvent contribution into the overall cytotoxicity of chemical reactions by the example of synthesis of 1,1'-biphenyl from aryl halide and phenylboronic acid. Two standard solvents (ethanol and N-methylpyrrolidone) and four ionic liquids (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, and cholinium bis(trifluoromethylsulfonyl)imide) were analyzed.
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