期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 95, 页码 13238-13241出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc04395e
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资金
- Science and Engineering Research Board (SERB) of the Department of Scienceand Technology (DST), Govt. of India [CRG/2019/000236]
- IISER Mohali
- UGC, New Delhi
A Pd-catalyzed direct method has been developed for accessing 1,3-disubstituted indolizines in moderate to good yields.
A Pd-catalyzed direct method has been developed to access 1,3-disubstituted indolizines. This reaction proceeds through a regiospecific annulation of terminal alkynes with 2-pyridinyl-substituted p-quinone methides and, in most of the cases, the desired 1,3-disubstituted indolizines were obtained in moderate to good isolated yields. The control experiments suggested that the reaction does proceed through a substrate-controlled regiospecific formal [3 + 2]-annulation pathway.
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