期刊
CRYSTENGCOMM
卷 24, 期 46, 页码 8060-8069出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ce01033j
关键词
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资金
- National Natural Science Foundation of China [81872760]
- Natural Science Foundation of Guangdong province [2021A11515011251]
- Guangdong scientific scheme [2021A0505030032]
- Chinese University of Hong Kong
In this study, Guanidinium-naphthalenedisulfonic acid (GNPS) was used as a molecular catcher to encapsulate liquid guests 1-8. The aromatic cavity of GNPS, with hydrogen bonding and enhanced C-H center dot center dot center dot pi interactions, proved to be a useful tool for the structural determination of liquid molecules.
Guanidinium-naphthalenedisulfonic acid (GNPS) was used as a molecular catcher because (i) it contains a cavity and channel in the network; (ii) NH2+ can be used as a hydrogen bond donor, and SO3- can be used as a hydrogen bond acceptor; (iii) the co-planar naphthalene rings can form aromatic interactions with guest molecules. The liquid guests 1-8 [(-)-isopulegol (1), (-)-menthyl acetate (2), isoeugenol (3), 2,6-dimethylaniline (4), methyleugenol (5), 2,6-diisopropylaniline (6), methyl salicylate (7) and L(-)-carvone (8)] are successfully encapsulated in the cavity of GNPS and eight new crystals were obtained. Both aromatic and non-aromatic molecules form hydrogen bonds and C-H center dot center dot center dot pi interactions with GNPS. Co-crystallization of 1-4 with GNPS led to stronger C-H center dot center dot center dot pi interactions as compared to the previously reported GBPS. Furthermore, compounds 5-8 which were not co-crystallized with GBPS were found to be encapsulated in the cavity of GNPS. We found that the aromatic cavity of GNPS with hydrogen bonding and enhanced C-H center dot center dot center dot pi interactions can be regarded as a useful tool for the structural determination of liquid molecules. Furthermore, the correct absolute configurations of 1, 2 and 8 can be assigned based on the small Flack parameters because of the presence of sulfur atoms in the host molecule GNPS.
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