期刊
ENERGY TECHNOLOGY
卷 4, 期 10, 页码 1200-1208出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.201600074
关键词
catalysis; chemical looping; ethane; oxidative dehydrogenation; redox reaction
资金
- Advanced Research Project Agency-Energy (ARPA-E) of the US Department of Energy [DE-AR0000327]
- Kenan Institute
The current study investigates a chemical-looping-based oxidative dehydrogenation (CL-ODH) concept for ethane-to-ethylene conversion. In this cyclic redox scheme, an oxide-based redox catalyst is used to selectively combust hydrogen from ethane dehydrogenation. As the hydrogen product limits ethane conversion, insitu oxidation of hydrogen enhances the ethane conversion and ethylene yield. Moreover, heat required in ODH is compensated by re-oxidation of the oxygen-deprived redox catalyst, enabling auto-thermal operation for the overall process. Compared to steam cracking, CL-ODH can potentially achieve higher efficiency with lower CO2 and NOx emissions. Silica and magnesia-supported manganese oxides are investigated. It is determined that unpromoted Mn/SiO2 and Mn/MgO redox catalysts exhibit low selectivity towards ethylene. The addition of promoters such as sodium and tungsten renders effective redox catalysts with satisfactory activity, selectivity, oxygen carrying capacity, and redox stability.
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