期刊
CHEMELECTROCHEM
卷 3, 期 11, 页码 1741-1745出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201600221
关键词
conductivity; poly(ethylene oxide); polymer electrolytes; sodium bis(fluorosulfonyl)imide; sodium-ion batteries
资金
- National Key Technologies RD Program [2016YFB0901504]
- National Natural Science Foundation of China [51222210, 11234013]
- One Hundred Talent Project of the Chinese Academy of Science
Sodium-ion batteries (SIBs), a promising substitute for lithiumion batteries (LIBs), are considered to have the potential to be employed in large-scale energy storage systems with lower cost and enhanced safety as primary concerns. Solid polymer electrolyte (SPE)-based SIBs will more likely meet these demands, because of their good flame resistance and excellent flexibility compared with conventional organic liquid-electrolyte-based SIBs. Here, we describe an SPE composed of sodium bis(fluorosulfonyl) imide (NaFSI) and poly(ethylene oxide) (PEO). The NaFSI/PEO (molar ratio of EO/Na+ = 20) blended polymer electrolyte exhibits a low glass transition temperature (i.e. -37.9 8 degrees C), relatively high ionic conductivity (i.e. & 4.1 V 10(-4) Scm(-1) at 808 degrees C), and enough electrochemical and thermal stability for application in SIBs. Most importantly, the NaFSI/PEO blended polymer electrolyte displays excellent interfacial stability with Na metal in Na/Na cells and good cycling performance in prototype cells with Na0.67Ni0.33Mn0.67O2 as the cathode material. All of these properties make NaFSI-based SPEs promising candidates for use in SIBs.
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