期刊
CHEM CATALYSIS
卷 2, 期 11, 页码 2965-2985出版社
CELL PRESS
DOI: 10.1016/j.checat.2022.08.020
关键词
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资金
- National Key R&D Program of China [2021YFA1500100]
- NSFC [21821002, 91856201]
- Science and Technology Commission of Shanghai Municipality [19590750400, 21520780100]
- Tencent Foundation through the XPLORER PRIZE
- China Postdoctoral Science Foundation [2021M693279]
This review provides an overview of the recent progress on cobalt-catalyzed enantioselective C-H functionalization reactions, including synthetic strategies, reactivities, selectivities, proposed mechanisms, and potential upcoming opportunities.
Enantioselective functionalization of C-H bonds offers a powerful solution and transformative tool for the step- and atom-economical construction of chiral molecular complexity. However, for a long time, this area was dominated by 4d and 5d transition metal catalysts. Recently, cobalt, as a 3d transition metal and group 9 metal, has earned considerable attention. Indeed, enantioselective C-H functionalization reactions enabled by cobalt catalysis have progressed rapidly in the past decade. In this review, we provide an overview of recent progress on cobalt-catalyzed enantioselective C-H functionalization reactions, including synthetic strategies, reactivities, selectivities, proposed mechanisms, and potential upcoming opportunities.
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