期刊
CHEM CATALYSIS
卷 2, 期 11, 页码 2876-2888出版社
CELL PRESS
DOI: 10.1016/j.checat.2022.09.048
关键词
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资金
- National Key R&D Program of China [2021YFF0701604, 2021YFF0701704]
- National Natural Science Foundation of China [22025103, 21831002, 22001109, 22271133, 22101122]
- Guangdong Innovative Program [2019BT02Y335]
- Guangdong Provincial Key Laboratory of Catalysis [2020B121201002]
- Shenzhen Special Funds [JCYJ20200109141001789]
- Great Bay University
Transition metal-catalyzed C-P coupling reactions play a significant role in constructing P-stereogenic centers, with the specific stereochemical mechanism depending on the phosphorus starting materials used. Recent developments in asymmetric catalysis have led to efficient kinetic resolution and dynamic kinetic asymmetric C-P coupling of racemic P-stereogenic compounds.
The transition metal-catalyzed C-P coupling reaction represents an effective strategy for the construction of P-stereogenic centers. These reactions involve different stereochemical mechanistic details depending on the phosphorus starting materials employed. The stereospecific transition metal-catalyzed C-P coupling of enantioenriched P-stereogenic compounds was mainly investigated in the early days. With the development of asymmetric catalysis, corresponding efficient kinetic resolution and dynamic kinetic asymmetric C-P coupling of racemic P-stereogenic starting compounds have recently been disclosed. This perspective discusses the impressive advances and provides an outlook on the directions of further developments.
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