3.8 Article

Synthesis of Carbon-Based Quantum Dots Using Lemon Juice under Hydrothermal Method

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UNIMAP PRESS

关键词

Carbon quantum dots; hydrothermal method; lemon juice; photoluminescence; quantum yield percentage

资金

  1. Fundamental Research Grant Scheme from the Ministry of Higher Education Malaysia [FRGS/1/2021/STG05/XMU/02/2]
  2. Xiamen University Malaysia Research Fund from Xiamen University Malaysia [XMUMRF/2019-C4/IENG/0023]

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This research successfully synthesized carbon-based quantum dots (CQDs) using pure lemon juice and a hydrothermal method. The addition of onion juice improved the quantum yield percentage of CQDs, with the optimal lemon-onion ratio found to be 8:2. The non-toxic CQDs, made from natural resources without the use of chemicals, have potential applications in various fields.
In this research, pure lemon juice was used to synthesize carbon-based quantum dots (CQDs) using hydrothermal method. Heated at 120 degrees C for a period of 3 hours, CQDs were successfully synthesized. The properties of CQDs were investigated by both FTIR and fluorescence spectrophotometer. Successful results show satisfactory optical properties and good water solubility from the CQDs. To further increase the quantum yield percentage of CQDs, onion juice was added to pure lemon juice at lemon-onion ratio of 8:2. The CQDs synthesized showed improved results with unexpected optical properties, strong water solubility as well as higher quantum yield percentage of 1.349%. Further investigation was done to find the optimal lemon-onion ratio for best quantum yield percentage results with different lemon-onion ratio. Results proves lemon-onion ratio of 8:2 is the optimal ratio. The CQDs synthesized are non-toxic due to the use of natural resources as its main materials as well as zero addition of chemicals throughout the synthesis process. Its zero-toxicity could benefit consumers in terms of consumables, such as toiletries, and water quality monitoring industry, such as heavy metal sensing and free chlorine sensing, as well as in medical field, such as bio-imaging and nanomedicine. Moreover, the by-products after synthesis are degradable, thus it would not create any long-lasting wastes. This could benefit the zero waste direction the world is heading towards.

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