Strongly overdoped La2-xSrxCuO4: Evidence for Josephson-coupled grains of strongly correlated superconductor

The interpretation of how superconductivity disappears in cuprates at large hole doping has been controversial. To address this issue, we present an experimental study of single-crystal and thin film samples of La2-xSrxCuO4 (LSCO) with x 0.25. In particular, measurements of bulk susceptibility on LSCO crystals with x = 0.25 indicate an onset of diamagnetism at Tc1 = 38.5 K, with a sharp transition to a phase with full bulk shielding at Tc2 = 18 K, independent of field direction. Strikingly, the in-plane resistivity only goes to zero at Tc2. Inelastic neutron scattering on x = 0.25 crystals confirms the presence of low-energy incommensurate magnetic excita-tions with reduced strength compared to lower doping levels. The ratio of the spin gap to Tc2 is anomalously large. Our results are consistent with a theoretical prediction for strongly overdoped cuprates by Spivak, Oreto, and Kivelson, in which superconductivity initially develops within disconnected self-organized grains characterized by a reduced hole concentration, with bulk superconductivity occurring only after superconductivity is induced by proximity effect in the surrounding medium of higher hole concentration. Beyond the superconducting-to-metal transition, local differential conductance measurements on an LSCO thin film suggest that regions with pairing correlations survive, but are too dilute to support superconducting order. Future experiments will be needed to test the degree to which these results apply to overdoped cuprates in general.

Automated summary

The interpretation of how superconductivity disappears in cuprates at large hole doping has been controversial. To address this issue, we studied La2-xSrxCuO4 (LSCO) samples with x=0.25. Our experimental results show that in LSCO crystals with x=0.25, there are two superconducting transition temperatures, Tc1 and Tc2, where Tc1 is 38.5 K and indicates the onset of diamagnetism, while Tc2 is 18 K and represents full bulk shielding. Moreover, we found that in strongly overdoped cuprates, superconductivity initially develops within disconnected self-organized grains characterized by reduced hole concentration, and there are still some regions with pairing correlations, but they are too dilute to support superconducting order.