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Synthesis of Aryl/Heteroaryl Selenides Using Transition Metals Catalyzed Cross Coupling and CH Activation

期刊

CURRENT ORGANIC CHEMISTRY
卷 26, 期 15, 页码 1470-1484

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BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1385272827666221103104321

关键词

Cross-coupling; C-H activation; transition metal; selenides; homogeneous and heterogenous catalysis; organic compounds

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This article reviews the recent advances in the synthesis of aryl and heteroaryl selenides through homogeneous and heterogeneous transition metal catalyzed cross-coupling reactions and directed selenylation via CH bond activations in the past decade.
Aryl and heteroaryl selenides are an important class of organic compounds and their synthesis has been widely studied all over the world in the last two decades. Transition metals catalysed cross-coupling and directed CH activation in unactivated arenes in the presence of diselenides/aryl selenols are found to be the most important tools for their synthesis. In recent years different transition metal catalysts were found to be effective to perform CSe cross-coupling in both aryl and heteroaryl rings. The present review article covers all the recent advances made in the last ten years in the field of the synthesis of aryl and heteroaryl selenides through homogeneous and heterogeneous transition metals catalyzed cross-coupling reactions and directed selenylation via CH bond activations.

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